2,7-dimethylacridine-3,6-diyl-bis-azaneylylidene-bis(methaneylylidene)diphenol | 1430746-96-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 2,7-dimethylacridine-3,6-diyl-bis-azaneylylidene-bis(methaneylylidene)diphenol
• 英文别名: 2-[[6-[(2-Hydroxyphenyl)methylideneamino]-2,7-dimethylacridin-3-yl]iminomethyl]phenol
• CAS: 1430746-96-5
• 化学式: C₂₉H₂₃N₃O₂
• 分子量: 445.521
• InChiKey: KPOJCATUXVJDDO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  34
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  78.1
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  copper(II) choride dihydrate 、 2,7-dimethylacridine-3,6-diyl-bis-azaneylylidene-bis(methaneylylidene)diphenol 在 三乙胺 作用下， 以 乙腈 为溶剂， 反应 24.0h， 以89%的产率得到
  参考文献：
  名称：

  Co ^II and Cu ^II Fluorescent Complexes with Acridine‐Based Ligands

  摘要：

  The condensation reaction of salicylaldehyde or 2‐hydroxynaphthaldehyde with a diamino organic group (Acridine Yellow or diaminoacridine) resulted in the Schiff‐base ligands ACRI‐1, ACRI‐2 and ACRI‐3, with the last two hitherto unknown. Fluorescent ACRI‐1, ACRI‐2 and ACRI‐3 were designed to provide iminophenolic binding pockets for two transition metals and ferromagnetic exchange between the metals. Following our report on the complex [Co2(ACRI‐1)2] (1Co), we report herein the reactions of ACRI‐1, ACRI‐2 and ACRI‐3 with CoII and CuII salts, which afforded the new fluorescent complexes [Cu2(ACRI‐1)2] (1Cu), [Co2(ACRI‐2)2] (2Co), [Cu2(ACRI‐2)2] (2Cu), [Co2(ACRI‐3)2(H2O)4] (3Co) and [Cu2(ACRI‐3)2] (3Cu).

  DOI：

  10.1002/ejic.201600297
• 作为产物：
  描述：

  反应 2.0h， 生成 2,7-dimethylacridine-3,6-diyl-bis-azaneylylidene-bis(methaneylylidene)diphenol
  参考文献：
  名称：

  完整沉积在HOPG上的稳健CoII荧光配合物的表征

  摘要：

  据报道，基于中央a啶黄核的新型二亚胺荧光配体ACRI-1及其配位化合物[Co 2（ACRI-1）2 ]（1）是一种荧光弱的铁磁体。由于the啶黄色荧光团的强荧光，当配体与Co II配位时，它不能完全淬灭。研究了本体配合物1的磁性及其在溶液中的稳定性。综合大楼1已从溶液中沉积到高度有序的热解石墨（HOGP）上。制备的薄膜的特征在于原子力显微镜，飞行时间二次离子质谱（TOF-SIMS），掠入射X射线衍射（GIXRD），X射线吸收光谱（XAS），X射线磁性圆二色性（XMCD）和理论计算。数据表明，该配合物坚固且在石墨表面上保持完好无损。

  DOI：

  10.1002/chem.201402814

文献信息

• New nanostructured materials: Nanostructuration of a fluorescent magnet based on acridine yellow
  作者：Daniel Reta Mañeru、María José Heras Ojea、Lidia Rosado、Guillem Aromí、Juan Zuazo、German Castro、E. Carolina Sañudo

  DOI：10.1016/j.poly.2013.03.013

  日期：2013.12

  In this paper we report the synthesis and characterization of a new fluorescent ligand, ACRI-1 and its Co(II) coordination complex 1, [Co-2(ACRI-1)(2)]. Complex 1 has been characterized by X-ray crystallography, magnetism and paramagnetic proton NMR. Nanostructuration of complex 1 has been achieved as monodisperse fluorescent nanoparticles and as thin layers on a HOPG surface. The thin layers have been characterized by AFM and GIXRD. (C) 2013 Elsevier Ltd. All rights reserved.
• Microwave assisted synthesis in coordination chemistry
  作者：Alba Pons-Balagué、María José Heras Ojea、Marisol Ledezma-Gairaud、Daniel Reta Mañeru、Simon J. Teat、Jose Sánchez Costa、Guillem Aromí、E. Carolina Sañudo

  DOI：10.1016/j.poly.2012.07.051

  日期：2013.3

  Microwave assisted synthesis is presented as a very useful tool in coordination chemistry. The synthesis assisted by microwave radiation has proven to be an excellent tool for the achievement of new structural types of polynuclear transition metal complexes. Several reaction conditions are studied and the results reported here. New examples of complexes of Mn, Co and Ni are reported along with their characterization. (C) 2012 Elsevier Ltd. All rights reserved.