cyclohexyl(2-methoxyethyl)phosphane | 201554-67-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: cyclohexyl(2-methoxyethyl)phosphane
• CAS: 201554-67-8
• 化学式: C₉H₁₉OP
• 分子量: 174.223
• InChiKey: AWIRVBXSQLYAEI-UHFFFAOYSA-N

物化性质

• 沸点：
  242.0±19.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.64
• 重原子数：
  11.0
• 可旋转键数：
  4.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.23
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  cyclohexyl(2-methoxyethyl)phosphane 、 烯丙基三甲基硅烷 反应 18.0h， 以58%的产率得到cyclohexyl-(2-methoxyethyl)-(3-trimethylsilylpropyl)phosphane
  参考文献：
  名称：

  Stoichiometric and Catalytic Reactions of the Polysiloxane-Bound (Ether-Phosphine)Rhodium(I) Complex [ClRh(PO)(P ∼ O)] in Interphases

  摘要：

  AbstractThe reaction of four equivalents of the monomeric trimethoxysilyl(T)‐functionalized ether‐phosphine ligand CyP(CH2CH2OCH3)(CH2)3SiR3 (R = OMe [1 a(T0)], Me [1 b]) with [{μ‐ClRh(COE)2}2] yielded the monomeric pseudo 14 electron rhodium(I) complexes [ClRh(PO)(P∼O)] (2a(T0)2, 2 b). For the sol‐gel process the complex 2 a(T0)2 was protected by introduction of the volatile, reversibly binding ligand pyridine. Thus, the monomeric compound 2 a(T0)2 was co‐condensed with two and eight equivalents of the co‐condensation agent MeSi(OMe)2(CH2)6(MeO)2SiMe (D0‐C6‐D0) to give the polysiloxane‐bound congeners 2(Tn)2(Di‐C6‐Di)y (y = 2 and 8, respectively; i = 0–2; n = 0–3). The polysiloxane‐bound complex 2(Tn)2‐(Di‐C6‐Di)2 was treated with a variety of small molecules in the gas/solid and liquid/solid interphases. It was shown that a facile cleavage of the Rh‐O bond in the ether‐phosphine chelate occurred even in the solid state. The reaction of 2(Tn)2‐(Di‐C6‐Di)2 with carbon monoxide, carbon disulfide, and diphenylacetylene resulted in the irreversible coordination of the molecule to the metal. In the presence of pyridine, the polysiloxane‐bound complex 2(Tn)2‐(Di‐C6‐Di)2 oxidatively added hydrogen to give the octahedrally configurated complex [ClRhH2(Py)(P ∼ O)2] [6(Tn)2(Di‐C6‐Di)2]. Treatment of dry 2(Tn)2‐(Di‐C6‐Di)2 with ethene led to the reversible formation of the corresponding complex. Although the materials display low surface areas, at least 75% of the rhodium centers within the matrix are accessible to the rather bulky tolan molecules. The complexes 2(Tn)2(Di‐C6‐Di)y (y (y = 2, 8) show high activities and selectivities in the hydrogenation of tolan. The conversion was found to depend markedly on the amount of co‐condensate (D0‐C6‐D0) and on the polarity of the solvent. The polysiloxane‐bound complexes 2(Tn)2(Di‐C6‐Di)y are more active than their monomeric congener 2 a(T0)2.

  DOI：

  10.1002/chem.19970031116
• 作为产物：
  描述：

  2-氯乙基甲基醚 、 环已基膦 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 以75%的产率得到cyclohexyl(2-methoxyethyl)phosphane
  参考文献：
  名称：

  Stoichiometric and Catalytic Reactions of the Polysiloxane-Bound (Ether-Phosphine)Rhodium(I) Complex [ClRh(PO)(P ∼ O)] in Interphases

  摘要：

  AbstractThe reaction of four equivalents of the monomeric trimethoxysilyl(T)‐functionalized ether‐phosphine ligand CyP(CH2CH2OCH3)(CH2)3SiR3 (R = OMe [1 a(T0)], Me [1 b]) with [{μ‐ClRh(COE)2}2] yielded the monomeric pseudo 14 electron rhodium(I) complexes [ClRh(PO)(P∼O)] (2a(T0)2, 2 b). For the sol‐gel process the complex 2 a(T0)2 was protected by introduction of the volatile, reversibly binding ligand pyridine. Thus, the monomeric compound 2 a(T0)2 was co‐condensed with two and eight equivalents of the co‐condensation agent MeSi(OMe)2(CH2)6(MeO)2SiMe (D0‐C6‐D0) to give the polysiloxane‐bound congeners 2(Tn)2(Di‐C6‐Di)y (y = 2 and 8, respectively; i = 0–2; n = 0–3). The polysiloxane‐bound complex 2(Tn)2‐(Di‐C6‐Di)2 was treated with a variety of small molecules in the gas/solid and liquid/solid interphases. It was shown that a facile cleavage of the Rh‐O bond in the ether‐phosphine chelate occurred even in the solid state. The reaction of 2(Tn)2‐(Di‐C6‐Di)2 with carbon monoxide, carbon disulfide, and diphenylacetylene resulted in the irreversible coordination of the molecule to the metal. In the presence of pyridine, the polysiloxane‐bound complex 2(Tn)2‐(Di‐C6‐Di)2 oxidatively added hydrogen to give the octahedrally configurated complex [ClRhH2(Py)(P ∼ O)2] [6(Tn)2(Di‐C6‐Di)2]. Treatment of dry 2(Tn)2‐(Di‐C6‐Di)2 with ethene led to the reversible formation of the corresponding complex. Although the materials display low surface areas, at least 75% of the rhodium centers within the matrix are accessible to the rather bulky tolan molecules. The complexes 2(Tn)2(Di‐C6‐Di)y (y (y = 2, 8) show high activities and selectivities in the hydrogenation of tolan. The conversion was found to depend markedly on the amount of co‐condensate (D0‐C6‐D0) and on the polarity of the solvent. The polysiloxane‐bound complexes 2(Tn)2(Di‐C6‐Di)y are more active than their monomeric congener 2 a(T0)2.

  DOI：

  10.1002/chem.19970031116