2,2-Dibenzyl-1,3-dioxane | 5695-83-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2,2-Dibenzyl-1,3-dioxane
• CAS: 5695-83-0
• 化学式: C₁₈H₂₀O₂
• 分子量: 268.356
• InChiKey: PRGAFDJZSSRTHE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,2-Dibenzyl-1,3-dioxane 在 三氟甲磺酸三甲基硅酯 、 dimethyl sulfide borane 作用下， 以 二氯甲烷 为溶剂， 以95%的产率得到3-(Dibenzylmethoxy)propan-1-ol
  参考文献：
  名称：

  Reduction of activated ketals with borane-dimethyl sulphide

  摘要：

  Borane-Dimethyl sulphide reduces ketals activated with TMSOTf at -78-degrees-C in dichloromethane. The scope and selectivity of the reagent has been investigated.

  DOI：

  10.1016/s0040-4039(00)74497-2
• 作为产物：
  描述：

  二苄基甲酮 、 1,3-丙二醇 在 对甲苯磺酸 作用下， 以 苯 为溶剂， 生成 2,2-Dibenzyl-1,3-dioxane
  参考文献：
  名称：

  A selectivity study of activated ketal reduction with borane dimethyl sulfide

  摘要：

  A chemo- and regioselectivity study of the reagent combination BH3.SMe2/TMSOTf for ketal reduction has been undertaken. It has revealed that simple 1,3-dioxanes reduce cleanly at low temperature in CH2Cl2 while simple 1,3-dioxolanes may give complete ring cleavage and dimerization products. A study of reduction of 4-substituted 1,3-dioxolanes has revealed a solvent-directed regioselectivity which in THF favors the secondary protected derivative. A mechanism is postulated to account for the selectivities based on recent thinking on acetal substitution reactions.

  DOI：

  10.1021/jo00076a041

文献信息

• Bartels Birgit, Hunter Roger, J. Org. Chem, 58 (1993) N 24, S 6756-6765
  作者：Bartels Birgit, Hunter Roger

  DOI：——

  日期：——
• SOLID CATALYST FOR OLEFIN POLYMERIZATION AND PROCESS FOR PRODUCING OLEFIN POLYMER
  申请人：Sumitomo Chemical Company, Limited

  公开号：US20130072648A1

  公开（公告）日：2013-03-21

  A solid catalyst for olefin polymerization and a process for producing an olefin polymer are provided. The polymer has a small content of a component which is dissolved out into a low temperature organic solvent, such as a low-molecular weight component and an amorphous component. The solid catalyst is obtained by bringing a solid catalyst component for olefin polymerization containing a titanium atom, a magnesium atom, a halogen atom, and an aliphatic carboxylate; an organoaluminum compound; and a compound represented by formula (I) into contact with each other: wherein R 1 is a hydrocarbyl group having 1 to 10 carbon atoms, R 2 is a hydrogen atom, a halogen atom or a hydrocarbyl group having 1 to 16 carbon atoms, and the R 1 the R 2 groups are independently the same or different, and the respective R 1 groups and R 2 groups may be joined with each other to form a ring.
• ELECTROLYTIC SOLUTION FOR LITHIUM-ION SECONDARY BATTERY, AND LITHIUM-ION SECONDARY BATTERY
  申请人：Murata Manufacturing Co., Ltd.

  公开号：US20210226253A1

  公开（公告）日：2021-07-22

  A lithium-ion secondary battery includes a positive electrode, a negative electrode, and an electrolytic solution. The electrolytic solution includes a solvent, an electrolyte salt, and at least one of a first dioxane compound or a second dioxane compound.