| 1416911-94-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• CAS: 1416911-94-8
• 化学式: C₄₃H₃₂N₂O₂
• 分子量: 608.739
• InChiKey: CPWOZQLYVTUCHN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.59
• 重原子数：
  47.0
• 可旋转键数：
  6.0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  44.0
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  在 吡啶 、 四氯化钛 、 锌 作用下， 以 四氢呋喃 为溶剂， 反应 12.0h， 以15%的产率得到21,21,58,58-Tetraethyl-15,27,52,64-tetrazanonadecacyclo[69.3.1.14,8.116,20.122,26.134,38.141,45.153,57.159,63.07,15.09,14.019,23.027,35.028,33.044,52.046,51.056,60.064,72.065,70]dooctaconta-1(75),2,4(82),5,7,9,11,13,16(81),17,19,22,24,26(80),28,30,32,34,36,38(79),39,41(78),42,44,46,48,50,53(77),54,56,59,61,63(76),65,67,69,71,73-octatriacontaene
  参考文献：
  名称：

  Synthesis and Optoelectrochemical Properties of Stilbenophanes Having Carbazole Moieties

  摘要：

  A series of stilbenophanes having N-arylated carbazole moieties possessing small and large cavities have been synthesized via McMurry coupling of the corresponding dialdehyde derived from N-arylation of carbazole with various dibromide followed by formylation. The electrochemical, photophysical, and complexation properties of all the stilbenophanes with electron-deficient guest molecules like TCNQ, TCNE, and PQT were also carried out at different concentrations.

  DOI：

  10.1055/s-0032-1317324
• 作为产物：
  描述：

  9,9'-(9,9-diethyl-9H-fluorene-2,7-diyl)bis(9H-carbazole) 、 N,N-二甲基甲酰胺 在 三氯氧磷 作用下， 以 1,2-二氯乙烷 为溶剂， 反应 12.0h， 以51%的产率得到
  参考文献：
  名称：

  Synthesis and Optoelectrochemical Properties of Stilbenophanes Having Carbazole Moieties

  摘要：

  A series of stilbenophanes having N-arylated carbazole moieties possessing small and large cavities have been synthesized via McMurry coupling of the corresponding dialdehyde derived from N-arylation of carbazole with various dibromide followed by formylation. The electrochemical, photophysical, and complexation properties of all the stilbenophanes with electron-deficient guest molecules like TCNQ, TCNE, and PQT were also carried out at different concentrations.

  DOI：

  10.1055/s-0032-1317324