1-(o-tolyloxy)naphthalene | 52681-94-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-(o-tolyloxy)naphthalene
• 英文别名: 2-Methylphenyl-1'-naphthylaether；1-(2-methylphenoxy)naphthalene
• CAS: 52681-94-4
• 化学式: C₁₇H₁₄O
• 分子量: 234.298
• InChiKey: ANYUNEZFVSLSID-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-溴代萘 、 邻甲酚 在 N-丁基咪唑 、 copper(l) chloride potassium carbonate 作用下， 以 十四烷 、 甲苯 为溶剂， 反应 16.0h， 以81%的产率得到1-(o-tolyloxy)naphthalene
  参考文献：
  名称：

  PROCESS FOR THE CATALYTIC SYNTHESIS OF DIARYL ETHERS

  摘要：

  描述了一种制备化学式为(I)Ar—O—Ar′的二芳基醚的过程  (I)其中Ar是芳基或取代芳基基团，Ar′是芳基、取代芳基、杂环芳基或取代杂环芳基基团，通过将化学式为(II)的芳基或化学式为(III)的芳氧盐  (II)Ar—OH   (III)其中Ar的含义与化学式(I)中相同，R为碱金属，与化学式(IV)的芳基或杂环芳基溴  (IV)Ar′—Br进行反应，其中Ar′的含义与化学式(I)中相同，其特征在于在铜(I)盐和1-取代咪唑作为催化剂体系的存在下进行反应。

  公开号：

  US20090143594A1

文献信息

• COMPOUND AND ORGANIC ELECTRONIC DEVICE USING THE SAME
  申请人：NICHEM FINE TECHNOLOGY CO., LTD.

  公开号：US20180155312A1

  公开（公告）日：2018-06-07

  Provided are a novel compound and an organic electronic device using the same. The novel corn pound is represented by the following Formula (I): wherein Y is an oxygen atom, a sulfur atom, or a sulfur dioxide group; X 1 and X 2 are each independently C(R a ), multiple (R a )s are the same or different, and the two (R a )s are joined together to form a first aryl ring; X 3 and X 4 are each independently C(R b ), multiple (R b )s are the same or different, and the two (R b )s are joined to form a second aryl ring or a heteroaryl ring.

  提供了一种新型化合物和使用该化合物的有机电子器件。该新型化合物由以下公式（I）表示：其中Y是氧原子、硫原子或二氧化硫基团；X1和X2分别独立地是C（Ra），多个（Ra）相同或不同，并且两个（Ra）结合在一起形成第一个芳基环；X3和X4分别独立地是C（Rb），多个（Rb）相同或不同，并且两个（Rb）结合在一起形成第二个芳基环或杂环。
• Process for the catalytic synthesis of diaryl ethers
  申请人：Saltigo GmbH

  公开号：US08304550B2

  公开（公告）日：2012-11-06

  Described is a process for preparing diaryl ethers of the formula (I) Ar—O—Ar′  (I) In which Ar is an aryl or substituted aryl group and Ar′ is an aryl, substituted aryl, heteroaryl or substituted heteroaryl group, by reacting an aryl of formula (II) or a aryloxy salt of formula (III) Ar—OH  (II) Ar—OR  (III) In which Ar has the same meaning as in formula (I) and R is an alkali metal, with an aryl or heteroaryl bromide of formula (IV) Ar′—Br  (IV) In which Ar′ has the same meaning as in formula (I), characterized in that the reaction is carried out in the presence of a copper(I)salt and a 1-substituted imidazole as catalyst system.

  描述了一种制备化合物(I)Ar—O—Ar'的过程，其中Ar是芳基或取代芳基基团，Ar'是芳基、取代芳基、杂环芳基或取代杂环芳基基团，通过将式(II)的芳基或式(III)的芳氧盐Ar—OH或Ar—OR（其中Ar与式(I)中相同，R为碱金属）与式(IV)的芳基或杂环芳基溴化物Ar'—Br（其中Ar'与式(I)中相同）反应，其特征在于在铜(I)盐和1-取代咪唑作为催化剂体系的存在下进行反应。
• Improved process for the catalytic synthesis of diaryl ethers
  申请人：Saltigo GmbH

  公开号：EP2065357A1

  公开（公告）日：2009-06-03

  Described is a process for preparing diaryl ethers of the formula (I)          Ar-O-Ar'     (I) In which Ar is an aryl or substituted aryl group and Ar' is an aryl, substituted aryl, heteroaryl or substituted heteroaryl group, by reacting an aryl of formula (II) or a aryloxy salt of formula (III)          Ar-OH     (II)          Ar-OR     (III) In which Ar has the same meaning as in formula (I) and R is an alkali metal, with an aryl or heteroaryl bromide of formula (IV)          Ar'-Br     (IV) In which Ar' has the same meaning as in formula (I), characterized in that the reaction is carried out in the presence of a copper(I)salt and a 1-substituted imidazole as catalyst system.

  描述了一种制备式 (I) 的二芳基醚的工艺 Ar-O-Ar' (I) 其中 Ar 是芳基或取代芳基，Ar'是芳基、取代芳基、杂芳基或取代杂芳基、 使式（II）的芳基或式（III）的芳氧基盐反应 Ar-OH (II) Ar-OR (III) 其中 Ar 与式（I）中的含义相同，R 为碱金属、 与式 (IV) 的芳基或杂芳基溴化物反应 Ar'-Br (IV) 其中 Ar' 的含义与式（I）中的相同、 其特征在于该反应是在铜（I）盐和 1-取代咪唑作为催化剂体系存在下进行的。
• Compound and organic electronic device using the same
  申请人：NICHEM FINE TECHNOLOGY CO., LTD.

  公开号：US10693077B2

  公开（公告）日：2020-06-23

  Provided are a novel compound and an organic electronic device using the same. The novel corn pound is represented by the following Formula (I): wherein Y is an oxygen atom, a sulfur atom, or a sulfur dioxide group; X1 and X2 are each independently C(Ra), multiple (Ra)s are the same or different, and the two (Ra)s are joined together to form a first aryl ring; X3 and X4 are each independently C(Rb), multiple (Rb)s are the same or different, and the two (Rb)s are joined to form a second aryl ring or a heteroaryl ring.

  本文提供了一种新型化合物和使用该化合物的有机电子设备。新型玉米镑由下式（I）表示： 其中，Y 是氧原子、硫原子或二氧化硫基团；X1 和 X2 各自独立为 C(Ra)，多个 (Ra)s 相同或不同，两个 (Ra)s 连接在一起形成第一个芳基环；X3 和 X4 各自独立为 C(Rb)，多个 (Rb)s 相同或不同，两个 (Rb)s 连接在一起形成第二个芳基环或杂芳环。
• Bio-inspired copper catalysts for the formation of diaryl ethers
  作者：Thomas Schareina、Alexander Zapf、Alain Cotté、Nikolaus Müller、Matthias Beller

  DOI：10.1016/j.tetlet.2008.01.036

  日期：2008.3

  Aryl bromides and phenols are coupled efficiently to the corresponding diaryl ethers in the presence of a practical Cu(I)/l-butylimidazole catalyst system. The convenient protocol is applied successfully to the synthesis of 16 different diaryl ethers in high yield and selectivity. (C) 2008 Elsevier Ltd. All rights reserved.