[Ni(1,3-diphenylpyrazole-4-carboxaldehyde thiosemicarbazone(1-))2] | 952100-89-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: [Ni(1,3-diphenylpyrazole-4-carboxaldehyde thiosemicarbazone(1-))2]
• CAS: 952100-89-9
• 化学式: C₃₄H₂₈N₁₀NiS₂
• 分子量: 699.485
• InChiKey: QLIOVJUUKVDELM-BPLVGVCGSA-L

反应信息

• 作为产物：
  描述：

  (E)-2-((1,3-diphenyl-1H-pyrazol-4-yl)methylene)hydrazine-1-carbothioamide 、 nickel(II) acetate tetrahydrate 以 甲醇 、 丙酮 为溶剂， 以46%的产率得到[Ni(1,3-diphenylpyrazole-4-carboxaldehyde thiosemicarbazone(1-))2]
  参考文献：
  名称：

  Transition metal complexes with thiosemicarbazide-based ligands. Part LVI: Nickel(II) complex with 1,3-diphenylpyrazole-4-carboxaldehyde thiosemicarbazone and unusually deformed coordination geometry

  摘要：

  Synthesis of a new nickel(II) complex, [Ni(Ph(2)PzTSC-H)(2)] with 1,3-diphenylpyrazole-4-carboxaldehyde thiosemicarbazone (Ph(2)PzTSC), is described. The compounds have been characterized by elemental and thermal analysis, molar conductivity and spectral (UV-Vis, IR, H-1 NMR, and C-13 NMR) measurements. In the case of complex the magnetic measurement has been also performed. Crystal and molecular structures of both the free ligand and the complex have been determined by single crystal X-ray analysis. It was found that the ligand coordinates in a bidentate NS fashion, in its deprotonated thioenolato form. The cis-square-planar geometry of the complex is significantly distorted tetrahedrally. The Cambridge Structural Database (CSD) study has been performed to obtain geometrical and structural informations on similar nickel(II) complexes in order to compare structural data. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.04.012