germanium(tetraphenylporphyrine) (2+) | 101953-22-4

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: germanium(tetraphenylporphyrine) (2+)
• CAS: 101953-22-4
• 化学式: C₄₄H₂₈GeN₄
• 分子量: 685.323
• InChiKey: DPJBRKXRIQPIBK-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  germanium(tetraphenylporphyrine) (2+) 以 异丙醇 、 丙酮 、 甲苯 为溶剂， 生成 germanium(tetraphenylporphyrine)(1+)
  参考文献：
  名称：

  C60与金属卟啉和芳烃的自由基离子之间的电子转移反应

  摘要：

  Electron-transfer reactions with C-60 leading to the singly reduced and oxidized radical ions, C-60(.-) and C-60(.+) have been studied by pulse radiolysis. pi-Radical anions of several metalloporphyrins (tetraphenyl- and tetrapyridylporphyrins) reduced C-60 With rate constants of (1-3) x 10(9) L mol(-1) s(-1), whereas metalloporphyrins which are reduced at the metal center (Ni-I, Cu-I, Cr-II) reacted with C-60 somewhat more slowly, with rate constants of (0.7-2.3) x 10(8) L mol(-1) s(-1). Sb(V)OEP(.-) (octaethylporphyrin) did not reduce C-60 (k less than or equal to 10(7) L mol(-1) s(-1)) and Sn-IV(Ph)(3)(Py)P-.- reacted in an equilibrium process (K = 14). Electron transfer from C-60 to several aromatic radical cations (derived from naphthalene, biphenyl, m-terphenyl, and trans-stilbene) also took place rapidly (k = (2.5-7.9) x 10(9) L mol(-1) s(-1)) to produce C-60(.+); the radical cations of anthracene and chrysene, on the other hand, did not exhibit any significant reactivity toward C-60.

  DOI：

  10.1021/j100068a022

文献信息

• One- and two-electron reduction of metalloporphyrins. Radiation chemical, photochemical, and electrochemical studies. Kinetics of the decay of .pi.-radical anions
  作者：M. C. Richoux、P. Neta、Anthony Harriman、S. Baral、P. Hambright

  DOI：10.1021/j100402a040

  日期：1986.5