N,N-dimethyl-phenanthrene-3-carboxamide | 101441-69-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: N,N-dimethyl-phenanthrene-3-carboxamide
• 英文别名: N,N-Dimethyl-phenanthren-3-carbamid
• CAS: 101441-69-4
• 化学式: C₁₇H₁₅NO
• 分子量: 249.312
• InChiKey: AEOHJEDJQJJBCS-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  (2-chlorobenzyl)triphenylphosphonium bromide 在 potassium tert-butylate 作用下， 以 四氢呋喃 、 二甲基亚砜 、 乙腈 为溶剂， 反应 12.5h， 生成 N,N-dimethyl-phenanthrene-3-carboxamide
  参考文献：
  名称：

  使用 CBZ6 作为能量转移光催化剂通过 E-Z 异构化实现合成

  摘要：

  考虑到化学选择性的区域选择性， Z-异构体和E-异构体的反应通常是不同的。 Z-异构体的合成在许多情况下是不可行的。能量转移 (EnT) E / Z光异构化可能会产生Z异构体。在这项工作中， CBZ6被证明是一种用于 C-C 或 C-N 双键E → Z异构化的 EnT 光催化剂。原位生成的肟和茋的Z-异构体的转化因此分别提供了所需的反向贝克曼重排产物和菲。

  DOI：

  10.1021/acs.orglett.4c01715

文献信息

• Personality disorders and psychoses form two distinct subgroups of homicide among female offenders
  作者：Hanna Putkonen、Jutta Collander、Marja-Liisa Honkasalo、Jouko Lönnqvist

  DOI：10.1080/09585180122116

  日期：2001.1

  This study examined circumstances of homicide by women in relation to their subsequent diagnoses. We investigated the written reports of forensic psychiatric examinations on 125 Finnish women who committed murder, attempted murder, manslaughter, or attempted manslaughter during 1982-92. In 86% of the cases the victims were adults, in 15% children. Intimate partners were the victims in 54% of the cases. Stabbing was the most frequent method and a quarrel the most frequent motive. The diagnoses of personality disorders and psychoses formed distinct subgroups. Psychotic women attacked proportionally more children than the personality disordered, who mainly attacked adults. Personality disordered women were more likely to have been intoxicated with alcohol at the time. Future treatment programmes and studies are suggested.