| 1198596-27-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 黄酮类化合物
• CAS: 1198596-27-8
• 化学式: C₄₁H₆₀O₅Si₂
• 分子量: 689.095
• InChiKey: LLVHWPRXMAMPFG-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  在 四氧化锇 、 N-甲基吗啉氧化物 作用下， 以 四氢呋喃 、 水 、 叔丁醇 为溶剂， 反应 4.0h， 以81%的产率得到
  参考文献：
  名称：

  Stable solid-supported leucoanthocyanidin variants for flavanoid biosynthesis elucidation

  摘要：

  Remarkable progress toward the complete elucidation of the biosynthesis of flavanoids has been accomplished during the last decade, but the final steps presumably involving the transformation of leucoanthocyanidins, which are highly unstable when free in aqueous solution into both anthocyanidins and proanthocyanidins still remain to be fully understood. Herein is described the synthesis of stabilized solid-supported leucoanthocyanidin variants that should serve as valuable tools for in vitro studies aimed at investigating the metabolism of these seemingly fleeting common precursors of two main classes of flavanoids. (C) 2009 Elsevier Ltd All lights reserved

  DOI：

  10.1016/j.tetlet.2009.09.045
• 作为产物：
  描述：

  在 sodium tetrahydroborate 作用下， 以 甲乙醚 为溶剂， 反应 0.25h， 以74%的产率得到
  参考文献：
  名称：

  Stable solid-supported leucoanthocyanidin variants for flavanoid biosynthesis elucidation

  摘要：

  Remarkable progress toward the complete elucidation of the biosynthesis of flavanoids has been accomplished during the last decade, but the final steps presumably involving the transformation of leucoanthocyanidins, which are highly unstable when free in aqueous solution into both anthocyanidins and proanthocyanidins still remain to be fully understood. Herein is described the synthesis of stabilized solid-supported leucoanthocyanidin variants that should serve as valuable tools for in vitro studies aimed at investigating the metabolism of these seemingly fleeting common precursors of two main classes of flavanoids. (C) 2009 Elsevier Ltd All lights reserved

  DOI：

  10.1016/j.tetlet.2009.09.045