2,5-dimethoxycinnamic acid and 3,5-dinitrocinnamic acid 1:1 complex | 137348-84-6

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 肉桂酸及其衍生物
• 英文名称: 2,5-dimethoxycinnamic acid and 3,5-dinitrocinnamic acid 1:1 complex
• CAS: 137348-84-6
• 化学式: C₉H₆N₂O₆*C₁₁H₁₂O₄
• 分子量: 446.37
• InChiKey: VAIQVADHYBUAKG-CUCLGLJNSA-N

反应信息

• 作为反应物：
  描述：

  2,5-dimethoxycinnamic acid and 3,5-dinitrocinnamic acid 1:1 complex 以 solid 为溶剂， 反应 120.0h， 以60%的产率得到(1S,2R,3S,4R)-3-(2,5-Dimethoxy-phenyl)-4-(3,5-dinitro-phenyl)-cyclobutane-1,2-dicarboxylic acid
  参考文献：
  名称：

  C–H ⋯ O hydrogen bonding and topochemistry in crystalline 3,5-dinitrocinnamic acid and its 1 : 1 donor–acceptor complex with 2,5-dimethoxycinnamic acid

  摘要：

  3,5-Dinitrocinnamic acid adopts an unusual crystal structure wherein C–H ⋯ O hydrogen bonds dictate the symmetry of the O–H ⋯ O network while its 1 : 1 molecular complex with 2, 5-dimethoxycinnamic acid is photoreactive in the solid state to yield an unsymmetrical cyclobutane dimer.

  DOI：

  10.1039/c39910001239