| 143933-64-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• CAS: 143933-64-6
• 化学式: C₂₀H₁₄N₃O₂*Cl*H₂O*Ni
• 分子量: 440.508
• InChiKey: IEKXKLVOZGIGIF-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  5-(1-phenyl-3-methyl-5-oxo-4-pyrazolinimino)-8-hydroxyquinoline 、 nickel dichloride 以 乙醇 为溶剂， 以48%的产率得到
  参考文献：
  名称：

  Carbonyl-bridged polymeric metal chelates of some quinolinol-containing 2-iminoketones

  摘要：

  Four-coordinate copper(II), nickel(II), cobalt(II) and cadmium(II) complexes formed by reaction of 8-hydroxyquinoline-5-iminoketones with M(II) chloride are described. Characterization of the isolated complexes has been performed on the basis of elemental and thermal analyses, electronic and IR spectral data as well as conductivity measurements. The ligands were found to act as monobasic bidentate N,O chelating agents. It is proposed that the complexes are polymeric with intermolecular carbonyl bridging. Tetrahedral or square planar stereochemical configuration is suggested for these complexes.

  DOI：

  10.1016/s0277-5387(00)83365-3