bis(3,5-dimethylpyrazol-1-yl)methanedinitratocopper(II) | 896727-32-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: bis(3,5-dimethylpyrazol-1-yl)methanedinitratocopper(II)
• CAS: 896727-32-5；95053-66-0
• 化学式: C₁₁H₁₆CuN₆O₆
• 分子量: 391.831
• InChiKey: FXFZLRMHPLMMCC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  苯并咪唑 、 bis(3,5-dimethylpyrazol-1-yl)methanedinitratocopper(II) 以 丙酮 为溶剂， 以84%的产率得到bis(3,5-dimethylpyrazol-1-yl)methanebis(1H-benzimidazole)nitratocopper(II) nitrate
  参考文献：
  名称：

  Synthesis of mixed-ligand copper(II) complexes containing bis(pyrazol-1-yl)methane ligands

  摘要：

  Complexes of copper(II) nitrate and chloride with several bis(pyrazol-1-yl)methane derivatives have been prepared and characterized by spectroscopic (IR, UV-Vis) and electrochemical (solution conductivity measurements, cyclic voltammetry) techniques. The complexes react with bidentate (2,2'-bipyridyl and acetylacetone) and monodentate (triphenylphosphine, 1H-benzimidazole, 1H-benzotriazole, 3,5-dimethyl-1H-pyrazole) ligands forming mixed-ligand complexes. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.03.016
• 作为产物：
  描述：

  copper(II) nitrate trihydrate 、 1-[(3,5-二甲基吡唑-1-基)甲基]-3,5-二甲基吡唑 以 丙酮 为溶剂， 以93%的产率得到bis(3,5-dimethylpyrazol-1-yl)methanedinitratocopper(II)
  参考文献：
  名称：

  Synthesis of mixed-ligand copper(II) complexes containing bis(pyrazol-1-yl)methane ligands

  摘要：

  Complexes of copper(II) nitrate and chloride with several bis(pyrazol-1-yl)methane derivatives have been prepared and characterized by spectroscopic (IR, UV-Vis) and electrochemical (solution conductivity measurements, cyclic voltammetry) techniques. The complexes react with bidentate (2,2'-bipyridyl and acetylacetone) and monodentate (triphenylphosphine, 1H-benzimidazole, 1H-benzotriazole, 3,5-dimethyl-1H-pyrazole) ligands forming mixed-ligand complexes. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.03.016