tripropyl orthoformate | 108994-56-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: tripropyl orthoformate
• 英文别名: Orthoameisensaeure-methyl-dipropylester；orthoformic acid methyl ester-dipropyl ester；Orthoameisensaeure-methylester-dipropylester；1-[Methoxy(propoxy)methoxy]propane
• CAS: 108994-56-5
• 化学式: C₈H₁₈O₃
• 分子量: 162.229
• InChiKey: BCXPZRPLHXLRKJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  11
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  tripropyl orthoformate 、 3-oxocyclobutanecarboxamide 在 硫酸 作用下， 以 乙醇 为溶剂， 反应 20.0h， 以57 g的产率得到
  参考文献：
  名称：

  3-氧代环丁基氨基甲酸叔丁酯的制备方法

  摘要：

  本发明属于医药技术领域，具体涉及一种3‑氧代环丁基氨基甲酸叔丁酯(I)的制备方法，所述方法包括如下步骤：化合物IV经保护生成化合物III，再经霍夫曼降解反应得到化合物II，最后脱保护得到化合物I。与现有技术相比，本发明技术路线成本低廉，反应条件温和，避免有毒的、危险系数较大的试剂的使用，绿色环保，具有良好的应用价值。

  公开号：

  CN111848423B
• 作为产物：
  描述：

  丙醇 、 1,1-二氯甲醚 生成 tripropyl orthoformate
  参考文献：
  名称：

  Gross,H.; Rieche,A., Chemische Berichte, 1961, vol. 94, p. 538 - 543

  摘要：

  DOI：

文献信息

• Organic amine salt compounds having CO2-donating anions and their use as foaming agent
  申请人：SHANDONG UNIVERSITY OF TECHNOLOGY

  公开号：US11261153B2

  公开（公告）日：2022-03-01

  An organic amine salt compounds of general formula An−[Bm+]p (I) is disclosed, wherein An− is a CO2-donating anion with a valence of −n, wherein n=1, 2 or 3; each Bm+ comprises: ammonium ion, hydrazinium ion and/or organic amine B cation; wherein m = 1 ⁢ - ⁢ 10 ; 0 < p ≤ n m ; and wherein An− is one or more selected from a group consisting of following anions: (a) carbamate orcarbazate; (b) carbonate; (c) formate; (d) bicarbonate; (e) organic monocarbonate; (f) organic poly-carbamate; (g) orthoformate; or (h) organic poly-carbonate. The compound of general formula (I) has at least one of hydroxyalkyl group linked to N atom, i.e., has alkanolamine residue. They can be used as polyurethane foaming agent, and most of them can be used as polystyrene foaming agent or polyvinyl choride foaming agent.

  本发明公开了一种通式为 An-[Bm+]p（I）的有机胺盐化合物，其中 An- 是价数为 -n 的二氧化碳供体阴离子，其中 n=1、2 或 3；每个 Bm+ 包括：铵离子、肼离子和/或有机胺 B 阳离子；其中 m = 1 - 10 ; 0 < p ≤ n m ; 其中 An- 是选自以下阴离子组成的组中的一个或多个：(a) 氨基甲酸酯或咔唑盐；(b) 碳酸酯；(c) 甲酸酯；(d) 碳酸氢盐；(e) 有机一碳酸盐；(f) 有机多氨基甲酸酯；(g) 原甲酸酯；或 (h) 有机多碳酸盐。通式（I）的化合物至少有一个羟烷基与 N 原子相连，即具有烷醇胺残基。它们可用作聚氨酯发泡剂，其中大部分可用作聚苯乙烯发泡剂或聚氯乙烯发泡剂。
• ORGANIC AMINE SALT COMPOUND HAVING ANIONS SERVING AS CO2 DONORS AND APPLICATION OF SAME AS FOAMING AGENT
  申请人：Shandong University Of Technology

  公开号：EP3466916B1

  公开（公告）日：2021-09-29
• ORGANIC AMINE SALT COMPOUNDS HAVING CO2-DONATING ANIONS AND THEIR USE AS FOAMING AGENT
  申请人：SHANDONG UNIVERSITY OF TECHNOLOGY

  公开号：US20190016673A1

  公开（公告）日：2019-01-17

  An organic amine salt compounds of general formula A n− [B m+ ] p (I) is disclosed, wherein A n− is a CO 2 -donating anion with a valence of −n, wherein n=1, 2 or 3; each B m+ comprises: ammonium ion, hydrazinium ion and/or organic amine B cation; wherein m = 1  -  10 ; 0 < p ≤ n m ; and wherein A n− is one or more selected from a group consisting of following anions: (a) carbamate orcarbazate; (b) carbonate; (c) formate; (d) bicarbonate; (e) organic monocarbonate; (f) organic poly-carbamate; (g) orthoformate; or (h) organic poly-carbonate. The compound of general formula (I) has at least one of hydroxyalkyl group linked to N atom, i.e., has alkanolamine residue. They can be used as polyurethane foaming agent, and most of them can be used as polystyrene foaming agent or polyvinyl choride foaming agent.
• Organic Amine Salt Compound Having Anions Serving as CO2 Donors and Application of Same as Foaming Agent
  申请人：Shandong University of Technology

  公开号：US20190152899A1

  公开（公告）日：2019-05-23

  A foaming agent comprising organic amine salt compounds of the following general formula A n− [B m+ ] p (I) is disclosed, wherein A n− is a CO 2 -donating anion with a valence of −n, wherein n=1, 2 or 3; each B m+ comprises: ammonium ion and/or organic amine (B) cation, wherein m = 1  -10;   0 < p ≤ n m ; and wherein A n− is one or more selected from following anions: (a) carbamate; (b) carbonate; (c) formate; (d) bicarbonate radical; (e) organic mono carbonate; (f) organic radical multi-carbamate; (g) orthoformate; or (h) organic radical poly-carbonate. The compound of the general formula (I) has at least one of hydroxyalkyl group linked to N atom, i.e., has alkanolamine residue. They can be used as polyurethane foaming agent, polystyrene foaming agent or polyvinyl choride foaming agent.