Bis[2-(acryloyloxy)ethyl] benzene-1,2-dicarboxylate | 14778-49-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Bis[2-(acryloyloxy)ethyl] benzene-1,2-dicarboxylate
• 英文别名: bis(2-prop-2-enoyloxyethyl) benzene-1,2-dicarboxylate
• CAS: 14778-49-5
• 化学式: C₁₈H₁₈O₈
• 分子量: 362.3
• InChiKey: OYDLJDVXYUAWKB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  26
• 可旋转键数：
  14
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  105
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  丙烯酸羟乙酯 、 三乙胺 、 邻苯二甲酰氯 在 4-二甲氨基吡啶 、 吩噻嗪 氮气 、 水 、 三乙胺盐酸盐 作用下， 以 四氢呋喃 为溶剂， 反应 11.5h， 以to yield 995 g (99%) of the desired product的产率得到Bis[2-(acryloyloxy)ethyl] benzene-1,2-dicarboxylate
  参考文献：
  名称：

  Abrasive articles incorporating addition polymerizable resins and

  摘要：

  本文描述了使用可涂层、可加聚合粘合剂前体组合物制成的磨料制品，以及制作这些制品的方法。该组合物包括反应性稀释剂化合物和优选的可加聚合树脂，反应性稀释剂是一种有机化合物，被选中特别有效地溶解氨基甲酸酯树脂。

  公开号：

  US05580647A1

文献信息

• Michael Acceptor Having Multiple Hydroxyl Groups, and Michael Addition Product Derived Therefrom
  申请人：Korea Research Institute of Chemical Technology

  公开号：US20130331600A1

  公开（公告）日：2013-12-12

  Provided is a Michael addition product prepared from a multifunctional acryl monomer having multiple hydroxyl groups allowing introduction of acryl functional groups, as a Michael acceptor, and a Michael donor. The Michael addition product is a novel multifunctional compound having an oligomer and a photoinitiator moiety in the molecule. Since it can be cured under a standard UV curing condition without having to add a photoinitiator, it is reduced to air pollution or health problem. Therefore the superior physical properties were obtained by cured coatings without surface tackiness. In addition, its hydroxyl groups allow, through isocyanate bonding or introduction of acryl groups, 3-dimensional crosslinking and molecular and compositional design for improving expandability, friction, and reactivity and hydrophilicity for self-adhesion, hardness of cured film, or the like. Consequently, a very useful, multifunctional or water-dispersible coating composition may be prepared.

  提供的是从具有多个羟基的多功能丙烯酸单体制备的Michael加成产物，允许引入丙烯酸功能团作为Michael受体和Michael给体。该Michael加成产物是一种新颖的多功能化合物，在分子中具有寡聚体和光引发剂基团。由于它可以在标准紫外光固化条件下固化，无需添加光引发剂，因此减少了空气污染或健康问题。因此，通过固化涂层获得了优越的物理性能，而无需表面粘性。此外，其羟基通过异氰酸酯键合或引入丙烯基，允许进行三维交联和分子和组成设计，以改善可扩展性、摩擦、反应性和亲水性，用于自粘附、固化膜的硬度等。因此，可以制备非常有用的多功能或水分散性涂料组合物。
• INKJET INKS FOR MANUFACTURING PRINTED CIRCUIT BOARDS
  申请人：Agfa-Gevaert NV

  公开号：US20210002500A1

  公开（公告）日：2021-01-07

  A method of manufacturing a Printed Circuit Board (PCB) wherein an inkjet printing step is used, characterized in that in the inkjet printing step a radiation curable inkjet ink comprising an adhesion promoter having a chemical structure according to Formula I is jetted and cured on a substrate, wherein X is selected from the group consisting of O and NR 3 , L 1 and L 2 independently represent a divalent linking group comprising from 2 to 20 carbon atoms, R 1 is selected from the group consisting of hydrogen, a substituted or unsubstituted alkyl group and a substituted or unsubstituted aryl group, R 2 is selected from the group consisting of a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group, a substituted or unsubstituted alkaryl group, a substituted or unsubstituted aralkyl group and a substituted or un-substituted (hetero)aryl group, R3 is selected from the group consisting of hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group, a substituted or unsubstituted alkaryl group, a substituted or unsubstituted aralkyl group and a substituted or unsubstituted (hetero)aryl group, n represents an integer from 0 to 4, any of L 1 , L 2 and R 2 may represent the necessary atoms to form a 5 to 8 membered ring.

  一种制造印刷电路板（PCB）的方法，其中使用喷墨打印步骤，其特征在于在喷墨打印步骤中，将一种辐射固化喷墨油墨喷射并固化在基板上，所述喷墨油墨包括具有根据式I的化学结构的粘附促进剂，其中X选自包括O和NR3的群，L1和L2独立地表示包含2至20个碳原子的二价连接基团，R1选自包括氢、取代或未取代的烷基基团和取代或未取代的芳基团的群，R2选自包括取代或未取代的烷基基团、取代或未取代的烯基基团、取代或未取代的炔基基团、取代或未取代的烷基芳基团、取代或未取代的芳基烷基团和取代或未取代的（杂）芳基团的群，R3选自包括氢、取代或未取代的烷基基团、取代或未取代的烯基基团、取代或未取代的炔基基团、取代或未取代的烷基芳基团、取代或未取代的芳基烷基团和取代或未取代的（杂）芳基团的群，n表示从0到4的整数，L1、L2和R2中的任何一个都可以表示形成5到8成员环所需的原子。
• CURABLE COMPOSITION FOR IMPRINTS AND PRODUCING METHOD OF POLYMERIZABLE MONOMER FOR IMPRINTS
  申请人：Kodama Kunihiko

  公开号：US20120076950A1

  公开（公告）日：2012-03-29

  Provided is a curable composition for imprints excellent in pattern transferability. Disclosed is a curable composition for imprints comprising a polymerizable monomer (A) and a polymerization initiator (B), which is substantially free from a polymer which contains at least one species of the polymerizable monomer (A) as a repeating unit.

  提供了一种适用于图案易传递的可治愈组合物。公开了一种适用于图案印记的可治愈组合物，包括可聚合单体（A）和聚合引发剂（B），其基本上不含至少一种将可聚合单体（A）作为重复单元的聚合物。
• CURABLE COMPOSITION, CURABLE INK, ACCOMMODATING CONTAINER, IMAGE FORMING DEVICE, IMAGE FORMING METHOD, CURED MATTER, AND ACRYLAMIDE COMPOUND
  申请人：MORITA Mitsunobu

  公开号：US20180127607A1

  公开（公告）日：2018-05-10

  A curable composition includes an acrylamide compound represented by the following Chemical formula 1: where R 1 represents an alkyl group having 1 to 6 carbon atoms, X represents an alkylene group having 1 to 6 carbon atoms, and Y represents the following Chemical formula 2 or the following Chemical formula 3, where R 2 represents an alkyl group having 1 to 10 carbon atoms and * represents a bond site with X, where R 2 represents an alkyl group having 1 to 10 carbon atoms and * represents a bond site with X.

  一种可治疗的组合物包括以下化学式1所表示的丙烯酰胺化合物：其中R1代表具有1至6个碳原子的烷基基团，X代表具有1至6个碳原子的烷基基团，Y代表以下化学式2或以下化学式3所示，其中R2代表具有1至10个碳原子的烷基基团，*代表与X形成键合位点，其中R2代表具有1至10个碳原子的烷基基团，*代表与X形成键合位点。
• POLYMERIZABLE LIQUID CRYSTAL COMPOUND, COMPOSITION, LIQUID CRYSTAL POLYMERIZATION FILM-KIND THEREOF AND USE THEREOF
  申请人：JNC CORPORATION

  公开号：US20170174992A1

  公开（公告）日：2017-06-22

  An object is to provide a polymerizable liquid crystal compound, a polymerizable liquid crystal composition containing the compound and liquid crystal polymerization film-kind capable of controlling chromatic dispersion characteristics and having low positive chromatic dispersion characteristics. An aspect can be exemplified in which the polymerizable liquid crystal compound is represented by formula (1): in which, in formula (1), G is a group composed of a quinoline skeleton, an isoquinoline skeleton, a quinoxaline skeleton or a quinazoline skeleton, A 1 is 1,4-phenylene or 1,4-cyclohexylene, Z 1 is a connecting group, m is an integer from 0 to 3, and R 1 is a group containing a polymerizable group.

  提供一种可聚合的液晶化合物，包含该化合物的可聚合液晶组合物以及能够控制色散特性并具有低正色散特性的液晶聚合膜。一种例子是该可聚合液晶化合物由式(1)表示：其中，在式(1)中，G是由喹啉骨架、异喹啉骨架、喹啉骨架或喹嗪骨架组成的基团，A1为1,4-苯基或1,4-环己基，Z1为连接基，m为0至3的整数，R1为含有可聚合基团的基团。