[Fe(phen)3]2[bis(dicyanobenzenedithiolate)nickelate(III)]*CH3CN | 955958-67-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: [Fe(phen)3]2[bis(dicyanobenzenedithiolate)nickelate(III)]*CH3CN
• CAS: 955958-67-5
• 化学式: C₂H₃N*C₃₂H₈N₈Ni₂S₈*C₃₆H₂₄FeN₆
• 分子量: 1515.9
• InChiKey: IQUBKQXRXUCGSH-UHFFFAOYSA-F

反应信息

• 作为产物：
  描述：

  tetra-n-butylammonium bis(dicyanobenzenedithiolate)nickelate(III) 、 [Fe(phen)₃](PF₆)₂ 、 乙腈 以 乙腈 为溶剂， 以50%的产率得到[Fe(phen)3]2[bis(dicyanobenzenedithiolate)nickelate(III)]*CH3CN
  参考文献：
  名称：

  Searching for switchable molecular conductors: Salts of [M(dcbdt)2] (M=Ni, Au) anions with [Fe(sal2-trien)]+ and [Fe(phen)3]2+

  摘要：

  Salts of [Fe-III(sal(2)-trien)](+)and [Fe-II(phen)(3)](2+) cations and M[(dcbdt)(2)](-) anions with M = Ni and All (dcbdt = dicyanobenzenedithiolate) with formula [Fe(sal(2)-trien)] [M(dcbdt)(2)] and [Fe(phen)(3)] [M(dcbdt)(2)](2) were obtained and characterized by single X-ray diffraction and magnetic measurements. None of these salts shows a clear spin crossover behaviour and their magnetic properties are due essentially to the cations in a high spin S = 5/2 and low spin states for the Fe-III and Fe-II salts respectively. The magnetic Ni sublattices in both compounds appear to have a negligible direct contribution to the magnetization but enhance the AF interactions in the cation sublattice, (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.03.015