双(4-(蒽-9-基)苯基)甲酮 | 1015228-71-3

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 中文名称: 双(4-(蒽-9-基)苯基)甲酮
• 英文名称: bis(4-(anthracen-9-yl)phenyl)methanone
• CAS: 1015228-71-3
• 化学式: C₄₁H₂₆O
• 分子量: 534.657
• InChiKey: MAYVDVWOHSNHQN-UHFFFAOYSA-N

物化性质

• 沸点：
  717.5±49.0 °C(Predicted)
• 密度：
  1.230±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  10.86
• 重原子数：
  42.0
• 可旋转键数：
  4.0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  17.07
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  双(4-(蒽-9-基)苯基)甲酮 在 四氯化钛 、 锌 作用下， 以 四氢呋喃 为溶剂， 反应 1.0h， 以56.7%的产率得到1,1,2,2-tetrakis(4-(anthracen-9-yl)phenyl)ethene
  参考文献：
  名称：

  Anthracene Effects on Organic Light Emitting Diode Performance of Tetra-Substituted Ethylene Derivatives

  摘要：

  We synthesized new bluish-green and sky-blue emitting materials, 1,1,2,2-tetra-kis(4'-tert-butylbiphenyl) ethane[TBBPE] and 1,1,2,2- tetrakis(4-(anthracen- 9-yl) phenyl) ethene[TAPE]. TBBPE and TAPE film showed PL maximum value of 511 nm and 492 nm. TBBPE OLED device showed bluish-green C. I. E. value of (0.236, 0.412) and high luminance efficiency of 5.02 cd/A at 10 mA/cm(2). TAPE device also showed sky-blue C. I. E. value of (0.213, 0.323) and 3.17 cd/A at 10 mA/cm(2). It is found that TBBPE shows better luminance efficiency than TAPE and TAPE device exhibits relatively lower operating voltage and better C. I. E. value than TBBPE device.

  DOI：

  10.1080/15421400701545387
• 作为产物：
  描述：

  9-溴蒽 在 四(三苯基膦)钯 、 正丁基锂 、 potassium carbonate 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 0.5h， 生成 双(4-(蒽-9-基)苯基)甲酮
  参考文献：
  名称：

  Anthracene Effects on Organic Light Emitting Diode Performance of Tetra-Substituted Ethylene Derivatives

  摘要：

  We synthesized new bluish-green and sky-blue emitting materials, 1,1,2,2-tetra-kis(4'-tert-butylbiphenyl) ethane[TBBPE] and 1,1,2,2- tetrakis(4-(anthracen- 9-yl) phenyl) ethene[TAPE]. TBBPE and TAPE film showed PL maximum value of 511 nm and 492 nm. TBBPE OLED device showed bluish-green C. I. E. value of (0.236, 0.412) and high luminance efficiency of 5.02 cd/A at 10 mA/cm(2). TAPE device also showed sky-blue C. I. E. value of (0.213, 0.323) and 3.17 cd/A at 10 mA/cm(2). It is found that TBBPE shows better luminance efficiency than TAPE and TAPE device exhibits relatively lower operating voltage and better C. I. E. value than TBBPE device.

  DOI：

  10.1080/15421400701545387