(HMeNHOH)(fac-Cl3-(dmso-S)3) | 259109-89-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (HMeNHOH)(fac-Cl3-(dmso-S)3)
• CAS: 259109-89-2
• 化学式: CH₆NO*C₆H₁₈Cl₃O₃RuS₃
• 分子量: 489.899
• InChiKey: GMZZNUGWRXJZIB-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  N-甲基羟胺盐酸盐 、 dichlorotetrakis(dimethylsulfoxide)ruthenium 以 水 为溶剂， 生成 (HMeNHOH)(fac-Cl3-(dmso-S)3)
  参考文献：
  名称：

  Hydrogen bonding effects on coordinated sulfoxides and relative role of intra- and inter-molecular interactions determining the dmso orientation in [RR′NHOH][fac-RuCl3(dmso)3] compounds: a crystallographic and molecular mechanics study

  摘要：

  Compounds with hydroxyl ammonium cations, [RR'NHOH][fac-RuCl3(dmso-S)(3)], with R = R' = H (1), R = Me, R' = H (2) and R = R' = Et (3), have been prepared and structurally characterized by X-ray analyses. The three compounds display chain-like structures, formed by hydrogen bonding between the hydroxyl ammonium cations and the chlorine and oxygen atoms of the ruthenium anion, H-bonding involving the dmso oxygen atoms causes a lengthening of the S-O bonds. The comparison of the solid state structures with results of Molecular Mechanics calculations show that the arrangement of the fac-dmso-S ligands is not determined by H-bonding or packing effects, but from intramolecular steric and electrostatic interactions. These give rise to hindered rotation about the Ru-S bonds. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-2860(99)00133-7