Acetic acid (E)-(1S,2R,3R,7R,8S,9S,10R,12R,16S)-9-[(2S,3R,4S,6R)-3-acetoxy-4-(acetyl-methyl-amino)-6-methyl-tetrahydro-pyran-2-yloxy]-3-ethyl-2,8,12,16-tetramethyl-5,13-dioxo-10-(2-oxo-ethyl)-4,17-dioxa-bicyclo[14.1.0]heptadec-14-en-7-yl ester | 77492-25-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Acetic acid (E)-(1S,2R,3R,7R,8S,9S,10R,12R,16S)-9-[(2S,3R,4S,6R)-3-acetoxy-4-(acetyl-methyl-amino)-6-methyl-tetrahydro-pyran-2-yloxy]-3-ethyl-2,8,12,16-tetramethyl-5,13-dioxo-10-(2-oxo-ethyl)-4,17-dioxa-bicyclo[14.1.0]heptadec-14-en-7-yl ester
• CAS: 77492-25-2
• 化学式: C₃₆H₅₅NO₁₂
• 分子量: 693.832
• InChiKey: DMRBAYOAHQQADM-TUAZIBHTSA-N

反应信息

• 作为产物：
  描述：

  乙酸酐 、 rosaramicin N-oxide 在 吡啶 作用下， 生成 Acetic acid (E)-(1R,3R,7S,9S,10R,11R,15R,16S,17S)-11-ethyl-3,7,10,16-tetramethyl-4,13,19-trioxo-8,12,18-trioxa-tricyclo[15.3.0.0^7,9]icos-5-en-15-yl ester 、 Acetic acid (E)-(1R,3R,7S,9S,10R,11R,15R,16S,17S)-19-acetoxy-11-ethyl-3,7,10,16-tetramethyl-4,13-dioxo-8,12,18-trioxa-tricyclo[15.3.0.0^7,9]icos-5-en-15-yl ester 、 Acetic acid (E)-(1S,2R,3R,7R,8S,9S,10R,12R,16S)-9-((2S,3S,6R)-3-acetoxy-6-methyl-4-oxo-tetrahydro-pyran-2-yloxy)-3-ethyl-2,8,12,16-tetramethyl-5,13-dioxo-10-(2-oxo-ethyl)-4,17-dioxa-bicyclo[14.1.0]heptadec-14-en-7-yl ester 、 Acetic acid (E)-(1S,2R,3R,7R,8S,9S,10R,12R,16S)-9-[(2S,3R,4S,6R)-3-acetoxy-4-(acetyl-methyl-amino)-6-methyl-tetrahydro-pyran-2-yloxy]-3-ethyl-2,8,12,16-tetramethyl-5,13-dioxo-10-(2-oxo-ethyl)-4,17-dioxa-bicyclo[14.1.0]heptadec-14-en-7-yl ester
  参考文献：
  名称：

  Chemical degradation and X-ray crystal structure of rosaramicin

  摘要：

  DOI：

  10.1016/0040-4039(80)88097-x