[Pd(glutarimidato)(2-(2-oxazolinyl)phenyl)(P(CH2CH2CN)3)] | 1030613-39-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [Pd(glutarimidato)(2-(2-oxazolinyl)phenyl)(P(CH2CH2CN)3)]
• 英文别名: [Pd(glut)(Phox)(P(CH2CH2CN)3)]
• CAS: 1030613-39-8
• 化学式: C₂₃H₂₆N₅O₃PPd
• 分子量: 557.885
• InChiKey: KLHXULZJVDQBSP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  di[(2-(2-oxazolinyl)phenyl)(μ-hydroxo)palladium(II)] 以 二氯甲烷 、 丙酮 为溶剂， 生成 [Pd(glutarimidato)(2-(2-oxazolinyl)phenyl)(P(CH2CH2CN)3)]
  参考文献：
  名称：

  Synthesis and characterization of new oxazoline-based palladacycles with bridging or terminal imidate ligands. Crystal structures of [{Pd(μ-dibromomaleimidate)(Phox)}2], [Pd(dibromomaleimidate)(Phox)(PPh3)] and [Pd(glutarimidate)(Phox)(PPh3)] (Phox=2-(2-oxazolinyl)phenyl))

  摘要：

  The dinuclear hydroxo complex [{Pd(mu-OH)(Phox)}(2)] (1) (Phox = 2-(2-oxazolinyl)phenyl) reacts in a 1:2 molar ratio with several imidate ligands to yield new cyclometallated palladium complexes ({Pd(mu-NCO)(Phox)}(2)] containing asymmetric imidate -NCO- bridging units. [-NCO- = succinimidate (succ) (1), phtalimidate (phtal) (2), maleimidate (mal) (3), 2,3-dibromomaleimidate (2,3-diBrmal) (4) and glutarimidate (glut) (5)]. The reaction of these complexes with tertiary phosphines provides novel mononuclear N-bonded imidate derivatives of the general formula [Pd(imidate)(Phox)(PR3)] [R = Ph (a), 4-F-C6H4 (b) or CH2CH2CN (c)]. The new complexes were characterized by partial elemental analyses and spectroscopic methods (IR, FAB, H-1, C-13 and P-31). The single-crystal structures of compounds 4, 4a and 5a have been established. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.02.001