mercury 8-selenoquinolinate | 88118-35-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: mercury 8-selenoquinolinate
• CAS: 88118-35-8
• 化学式: C₁₈H₁₂HgN₂Se₂
• 分子量: 614.817
• InChiKey: KTDJWDLFPICDMK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  di-(8-quinolinyl)diselenide 、 mercury dichloride 在 hydrochloric acid 、 hypophosphorous acid 、 sodium acetate 作用下， 以 乙醇 、 水 为溶剂， 生成 mercury 8-selenoquinolinate
  参考文献：
  名称：

  Synthesis and structure of Mercury 8-selenolquinolinate Hg(C9H6NSe)2: Crystal-chemical comparison of mercury 8-selenol-, 8-mercapto-, and 8-hydroxyquinolinates

  摘要：

  Mercury 8-selenolquinolinate was synthesized and studied by X-ray diffraction. In neutral Hg(C9H6NSe)(2), 8-selenolquinoline is a bidentate (S,N) ligand. The coordination polyhedron of mercury is a distorted tetrahedron or a seesaw (2Se + 2N). The bond lengths are as follows: Hg-Se, 2.4599(9) and 2.4606(9) angstrom; Hg center dot center dot center dot N, 2.497(6) and 2.513(6) angstrom. The SeHgSe bond angle is 166.07(3)degrees. Mercury 8-selenolquinolinate belongs to the class of chelates in which the five-membered chelate rings-Hg-Se-C-C-N-contain a donor selenium atom. The structures and the Hg-Se, Hg-S, Hg-O, and Hg-N bonds in mercury 8-selenol-, 8-mercapto-, and 8-hydroxyquinolinates were analyzed.

  DOI：

  10.1134/s0036023606010116