6-((2R,3S,4R,5R,6R)-3,4,5-Triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-ylmethyl)-3,6-dihydro-2H-pyran-2-carboxylic acid methyl ester | 188405-09-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 6-((2R,3S,4R,5R,6R)-3,4,5-Triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-ylmethyl)-3,6-dihydro-2H-pyran-2-carboxylic acid methyl ester
• CAS: 188405-09-6
• 化学式: C₂₂H₃₀O₁₂
• 分子量: 486.473
• InChiKey: YQXRMNRIGWAKNC-BNVJOHFHSA-N

反应信息

• 作为反应物：
  描述：

  6-((2R,3S,4R,5R,6R)-3,4,5-Triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-ylmethyl)-3,6-dihydro-2H-pyran-2-carboxylic acid methyl ester 在 palladium on activated charcoal 吡啶 、 甲醇 、 锂硼氢 、 氢气 、 sodium methylate 作用下， 以 甲醇 为溶剂， 反应 44.0h， 生成 (2S,6S)-6-benzoyloxymethyl-3,4,5,6-tetrahydro-2-[(2,3,4,6-tetra-O-benzoyl-α-D-glucopyranosyl)methyl]-pyran
  参考文献：
  名称：

  New access to C-disaccharide analogs of α, α-trehalose using an aqueous hetero Diels-Alder reaction

  摘要：

  C-disaccharide analogs of trehalose were prepared using an aqueous Diels-Alder reaction as a key step. The resulting major stereoisomer was shown by NMR spectroscopy analysis to have the correct (alpha, alpha') stereochemistry of trehalose. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0008-6215(96)00267-4
• 作为产物：
  描述：

  乙酸酐 、 在 吡啶 作用下， 反应 8.0h， 生成 6-((2R,3S,4R,5R,6R)-3,4,5-Triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-ylmethyl)-3,6-dihydro-2H-pyran-2-carboxylic acid methyl ester
  参考文献：
  名称：

  New access to C-disaccharide analogs of α, α-trehalose using an aqueous hetero Diels-Alder reaction

  摘要：

  C-disaccharide analogs of trehalose were prepared using an aqueous Diels-Alder reaction as a key step. The resulting major stereoisomer was shown by NMR spectroscopy analysis to have the correct (alpha, alpha') stereochemistry of trehalose. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0008-6215(96)00267-4