(1R,1aR,1bS,5R,5aR,6aR)-5-Hydroxy-1-isopropyl-5a-methyl-octahydro-cyclopropa[a]inden-2-one | 84071-89-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (1R,1aR,1bS,5R,5aR,6aR)-5-Hydroxy-1-isopropyl-5a-methyl-octahydro-cyclopropa[a]inden-2-one
• CAS: 84071-89-6
• 化学式: C₁₄H₂₂O₂
• 分子量: 222.327
• InChiKey: ITFMRNZZSUAEMY-WGQIVAOGSA-N

反应信息

• 作为反应物：
  描述：

  乙酸酐 、 (1R,1aR,1bS,5R,5aR,6aR)-5-Hydroxy-1-isopropyl-5a-methyl-octahydro-cyclopropa[a]inden-2-one 在 吡啶 、 乙酸酐 作用下， 生成 Acetic acid (1R,1aR,1bS,5R,5aR,6aR)-1-isopropyl-5a-methyl-2-oxo-decahydro-cyclopropa[a]inden-5-yl ester
  参考文献：
  名称：

  BIOMIMETIC CONVERSION OF EPOXYGERMACRENE-D TO A NOVEL SESQUITERPENE OF THE PLANTTORILIS JAPONICADC.

  摘要：

  Epoxygermacrene-D was treated with basic alumina to afford a new type of sesquiterpene, whose stereostructure was determined on the basis of its spectral data coupled with an X-ray crystallographic analysis of the corresponding ketone produced on CrO3 oxidation.

  DOI：

  10.1246/cl.1982.1681
• 作为产物：
  描述：

  epoxygermacrene-D 在 吡啶 、 aluminum oxide 、 氢氧化钾 、 二甲基硫 、 臭氧 作用下， 以 甲醇 、 正己烷 为溶剂， 反应 7.5h， 生成 (1R,1aR,1bS,5R,5aR,6aR)-5-Hydroxy-1-isopropyl-5a-methyl-octahydro-cyclopropa[a]inden-2-one
  参考文献：
  名称：

  BIOMIMETIC CONVERSION OF EPOXYGERMACRENE-D TO A NOVEL SESQUITERPENE OF THE PLANTTORILIS JAPONICADC.

  摘要：

  Epoxygermacrene-D was treated with basic alumina to afford a new type of sesquiterpene, whose stereostructure was determined on the basis of its spectral data coupled with an X-ray crystallographic analysis of the corresponding ketone produced on CrO3 oxidation.

  DOI：

  10.1246/cl.1982.1681