2-(Benzyldisulfanyl)-1-(4-methoxyphenyl)ethanone | 1429397-47-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-(Benzyldisulfanyl)-1-(4-methoxyphenyl)ethanone
• 英文别名: 2-(benzyldisulfanyl)-1-(4-methoxyphenyl)ethanone
• CAS: 1429397-47-6
• 化学式: C₁₆H₁₆O₂S₂
• 分子量: 304.434
• InChiKey: ZFZQRGNYAOGJIJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  20
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  76.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  硫氰酸苄酯 、 4-甲氧基苯乙酰硫氰酸酯 在 Amberlyst A-26(OH) 作用下， 以 水 为溶剂， 以27.8%的产率得到二苄基二硫
  参考文献：
  名称：

  An efficient metal-free synthesis of organic disulfides from thiocyanates using poly-ionic resin hydroxide in aqueous medium

  摘要：

  An efficient and metal-free method is described for the preparation of organic disulfides from alkyl and acyl methyl thiocyanates in the presence of poly-ionic resin hydroxide in aqueous medium. Further extension of this protocol has been tested using two different organyl thiocyanates to prepare unsymmetrical disulfides. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.02.070

文献信息

• An efficient metal-free synthesis of organic disulfides from thiocyanates using poly-ionic resin hydroxide in aqueous medium
  作者：Debasish Sengupta、Basudeb Basu

  DOI：10.1016/j.tetlet.2013.02.070

  日期：2013.5

  An efficient and metal-free method is described for the preparation of organic disulfides from alkyl and acyl methyl thiocyanates in the presence of poly-ionic resin hydroxide in aqueous medium. Further extension of this protocol has been tested using two different organyl thiocyanates to prepare unsymmetrical disulfides. (C) 2013 Elsevier Ltd. All rights reserved.