trans-[Ru(NH3)4(P(OCH3)3)2](2+) | 69934-30-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: trans-[Ru(NH3)4(P(OCH3)3)2](2+)
• 英文别名: trans-[Ru(NH3)4(P(OMe)3)2](2+)
• CAS: 69934-30-1
• 化学式: C₆H₃₀N₄O₆P₂Ru
• 分子量: 417.345
• InChiKey: YZSISOLHFJJAQH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-[Ru(NH3)4(P(OCH3)3)2](2+) 、 水 在 CF₃CO₂H 作用下， 以 further solvent(s) 为溶剂， 生成 trans-[Ru(NH3)4(P(OCH3)3)(H2O)](2+)
  参考文献：
  名称：

  Selective Photolabilization in trans-[Ru(NH₃)₄(P(III))H₂O]²⁺ and trans-[Ru(NH₃)₄(P(OR)₃)₂]²⁺ Complexes (P(III) = P(OR)₃, P(R)₃)

  摘要：

  Irradiation in the LF bands (1)A(1) --> (1)E(1) and (1)A(1g) --> (1)A(2g), (1)E(g) leads to NH3 photolabilization of trans-[Ru(NH3)(4)(P(III))H2O](2+) complexes and to NH3 and P(III) photolabilization of trans-[Ru(NH3)(4)(P(III))(2)](2+) species. For both series of complexes Phi(NH3) has essentially the same experimental value of 0.34 +/- 0.03 mol/einstein. The Phi(P(III)) values for the bis(phosphane) complexes trans-[Ru(NH3)(4)(P(III))(2)](2+) are in the 0.034-0.070 range for P(III) = P(OCH3)(3) and P(OC2H4Cl)(3). No clear relationship could be established between the cone angle theta of the phosphane or the formal potential E degrees'(Ru(III)/Ru(II)) and the corresponding Phi(NH3) and Phi(P(III)) data for the complexes studied. The NH3 ligand is selectively photolabilized when the trans-[Ru(NH3)(4)(P(III))(2)](2+) and the trans-[Ru(NH3)(4)(P(III))H2O](2+) species are irradiated with energies corresponding to the (1)A(1g) --> (1)A(2g) and (1)A(1) --> (1)A(2) transitions.

  DOI：

  10.1021/ic9509847