tert-butyl (Z)-2-[(2S,3R,4R,5R,6R)-3-(1,3-dioxoisoindol-2-yl)-4,5-dihydroxy-6-[[[2-[[2-[[2-[(2-methylpropan-2-yl)oxycarbonylamino]acetyl]amino]acetyl]amino]acetyl]amino]methyl]oxan-2-yl]oxy-3-(4-hydroxyphenyl)prop-2-enoate | 930578-36-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: tert-butyl (Z)-2-[(2S,3R,4R,5R,6R)-3-(1,3-dioxoisoindol-2-yl)-4,5-dihydroxy-6-[[[2-[[2-[[2-[(2-methylpropan-2-yl)oxycarbonylamino]acetyl]amino]acetyl]amino]acetyl]amino]methyl]oxan-2-yl]oxy-3-(4-hydroxyphenyl)prop-2-enoate
• CAS: 930578-36-2
• 化学式: C₃₈H₄₇N₅O₁₄
• 分子量: 797.816
• InChiKey: KDHTWFQBCXIXCW-ONLDEHTQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  57
• 可旋转键数：
  17
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  269
• 氢给体数：
  7
• 氢受体数：
  14

反应信息

• 作为反应物：
  描述：

  tert-butyl (Z)-2-[(2S,3R,4R,5R,6R)-3-(1,3-dioxoisoindol-2-yl)-4,5-dihydroxy-6-[[[2-[[2-[[2-[(2-methylpropan-2-yl)oxycarbonylamino]acetyl]amino]acetyl]amino]acetyl]amino]methyl]oxan-2-yl]oxy-3-(4-hydroxyphenyl)prop-2-enoate 在 一水合肼 、 三乙胺 作用下， 以 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 生成 tert-butyl (Z)-2-[(2S,3R,4R,5R,6R)-3-[(4-benzoylphenyl)methylamino]-4,5-dihydroxy-6-[[[2-[[2-[[2-[(2-methylpropan-2-yl)oxycarbonylamino]acetyl]amino]acetyl]amino]acetyl]amino]methyl]oxan-2-yl]oxy-3-(4-hydroxyphenyl)prop-2-enoate
  参考文献：
  名称：

  Nanometer-scale direct observation of the receptor for the leaf-movement factor in plant cell by a novel TEM probe

  摘要：

  Electron microscopy is a useful method for observing localization of some proteins in a cell. In this Letter, we report a nanometer-scale direct observation of the receptor for a bioactive substance of small molecular weight by using TEM (transmission electron microscopy). We developed a novel TEM probe compound (1) that is a modified leaf-movement factor with benzophenone as a photoaffinity group and FITC as an antigen that is recognized by a nano-gold bound anti-FITC antibody. By using probe 1, we revealed that the receptor for the leaf-movement factor of Cassia mimosoides is localized in the plasma membrane of the plant motor cell. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2006.12.128
• 作为产物：
  描述：

  t-butyl (Z)-2-(2'-deoxy-2'-phthalimido-6'-azido-6'-deoxy-β-D-galactopyranosyloxy)-3-p-hydroxyphenyl-2-acrylate 在 Lindlar's catalyst 氢气 作用下， 以 甲醇 、 N,N-二甲基甲酰胺 为溶剂， 生成 tert-butyl (Z)-2-[(2S,3R,4R,5R,6R)-3-(1,3-dioxoisoindol-2-yl)-4,5-dihydroxy-6-[[[2-[[2-[[2-[(2-methylpropan-2-yl)oxycarbonylamino]acetyl]amino]acetyl]amino]acetyl]amino]methyl]oxan-2-yl]oxy-3-(4-hydroxyphenyl)prop-2-enoate
  参考文献：
  名称：

  Nanometer-scale direct observation of the receptor for the leaf-movement factor in plant cell by a novel TEM probe

  摘要：

  Electron microscopy is a useful method for observing localization of some proteins in a cell. In this Letter, we report a nanometer-scale direct observation of the receptor for a bioactive substance of small molecular weight by using TEM (transmission electron microscopy). We developed a novel TEM probe compound (1) that is a modified leaf-movement factor with benzophenone as a photoaffinity group and FITC as an antigen that is recognized by a nano-gold bound anti-FITC antibody. By using probe 1, we revealed that the receptor for the leaf-movement factor of Cassia mimosoides is localized in the plasma membrane of the plant motor cell. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2006.12.128