1-vinyladamantan-4-one | 424826-49-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-vinyladamantan-4-one
• 英文别名: 5-Ethenyladamantan-2-one
• CAS: 424826-49-3
• 化学式: C₁₂H₁₆O
• 分子量: 176.258
• InChiKey: ZDGOSSMRROQALD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• Monomer having electron-withdrawing group and process for preparing the same
  申请人：——

  公开号：US20030059710A1

  公开（公告）日：2003-03-27

  A monomer containing an electron-withdrawing group of the present invention is represented by following Formula (a), (b) or (c): 1 wherein A 1 , A 2 , and A 3 are each a ring; R a , R b , R c , and R u are the same or different and are each a hydrogen atom or organic group; at least one of R s , R w and R v , at least one of R t and R w1 , and at least one of the two R w2 s are each an electron-withdrawing group, and the others are each a hydrogen atom or organic group; W 1 is a single bond or linkage group; and n denotes an integer of 2 to 25, where at least two of R a , R b , R c , R s , R t , R u , R v , R w , R w1 , R w2 , W 1 , and carbon atoms constituting ring A 1 , carbon atoms constituting ring A 2 , and carbon atoms constituting ring A 3 may be combined to form a ring, respectively. The electron-withdrawing groups in R s , R t , R v , R w , R w1 , and R w2 are, for example, groups each containing a fluorine atom. The monomer is useful as a raw material for photoresist polymeric compounds.

  本发明的含有电子吸引基团的单体由以下化学式(a)、(b)或(c)表示：其中A1、A2和A3各自为一个环；Ra、Rb、Rc和Ru相同或不同，各自为氢原子或有机基团；Rs、Rw和Rv中至少有一个，Rt和Rw1中至少有一个，两个Rw2中至少有一个为电子吸引基团，其他的为氢原子或有机基团；W1为单键或连接基团；n表示2到25的整数，其中至少有两个Ra、Rb、Rc、Rs、Rt、Ru、Rv、Rw、Rw1、Rw2、W1和构成环A1的碳原子、构成环A2的碳原子以及构成环A3的碳原子可以分别结合形成一个环。 Rs、Rt、Rv、Rw、Rw1和Rw2中的电子吸引基团，例如，是每个含有氟原子的基团。该单体可用作光刻胶聚合物化合物的原材料。
• MONOMERS HAVING ELECTRON-WITHDRAWING GROUPS AND PROCESSES FOR PREPARING THE SAME
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP1331216A1

  公开（公告）日：2003-07-30

  A monomer containing an electron-withdrawing group of the present invention is represented by following Formula (a), (b) or (c) : wherein A1, A2, and A3 are each a ring; Ra, Rb, Rc, and Ru are the same or different and are each a hydrogen atom or organic group; at least one of Rs, Rw and Rv, at least one of Rt and Rw1, and at least one of the two Rw2s are each an electron-withdrawing group, and the others are each a hydrogen atom or organic group; W1 is a single bond or linkage group; and n denotes an integer of 2 to 25, where at least two of Ra, Rb, Rc, Rs, Rt, Ru, Rv, Rw, Rw1, Rw2, W1, and carbon atoms constituting ring A1, carbon atoms constituting ring A2, and carbon atoms constituting ring A3 may be combined to form a ring, respectively. The electron-withdrawing groups in Rs, Rt, Rv, Rw, Rw1, and Rw2 are, for example, groups each containing a fluorine atom. The monomer is useful as a raw material for photoresist polymeric compounds.

  本发明中含有抽电子基团的单体由下式(a)、(b)或(c)表示： 其中 A1、A2 和 A3 各为一个环；Ra、Rb、Rc 和 Ru 相同或不同，各为一个氢原子或有机基团；Rs、Rw 和 Rv 中的至少一个，Rt 和 Rw1 中的至少一个，以及两个 Rw2 中的至少一个各为一个抽电子基团，其它各为一个氢原子或有机基团；W1是单键或连接基团；n表示2至25的整数，其中Ra、Rb、Rc、Rs、Rt、Ru、Rv、Rw、Rw1、Rw2、W1中的至少两个以及构成环A1的碳原子、构成环A2的碳原子和构成环A3的碳原子可分别组合成一个环。例如，Rs、Rt、Rv、Rw、Rw1 和 Rw2 中的抽电子基团是各自含有一个氟原子的基团。该单体可用作光阻聚合化合物的原料。
• High molecular compound, monomer compounds and photosensitive composition for photoresist, pattern forming method utilizing photosensitive composition, and method of manufacturing electronic components
  申请人：Kabushiki Kaisha Toshiba

  公开号：US20030235781A1

  公开（公告）日：2003-12-25

  Disclosed is a polymer compound for photoresist characterized in that the polymer compound is formed of a polymer compound having at least one skeleton represented by the following general formula (1), general formula (2A), general formula (2B) or general formula (2C): 1 (wherein R is an alicyclic skeleton; at least one of R x1 s is an electron-withdrawing group, the residual R x1 s being the same or different and being individually a hydrogen atom or monovalent organic group; with the proviso that R may contain a heteroatom, and that R and R x1 may be combined to form a ring; at least one of R x1 s is an electron-withdrawing group, the residual R x1 s being the same or different and being individually a hydrogen atom or monovalent organic group; R 2 s may be the same or different and are individually a hydrogen atom or monovalent organic group; and n is an integer ranging from 2 to 25; with the proviso that at least two carbon atoms selected from carbon atoms constituting R 2 and carbon atoms to which the R 2 s are connected may be combined to form a condensed ring).

  本发明公开了一种用于光刻胶的聚合物化合物，其特征在于该聚合物化合物是由至少一个骨架由以下通式(1)、通式(2A)、通式(2B)或通式(2C)表示的聚合物化合物形成的： 1 (其中 R 为脂环族骨架；R x1 中至少有一个是取电子基团，残余 R x1 s 相同或不同，且各自为氢原子或单价有机基团；但 R 可含有一个杂原子，且 R 和 R x1 可组合成一个环；R x1 中至少有一个是抽电子基团，残余的 R x1 s 相同或不同，且各自为氢原子或单价有机基团；R 2 s 可以相同或不同，且各自为氢原子或一价有机基团；n 为 2 至 25 之间的整数；但至少有两个碳原子选自构成 R 2 2 的碳原子和 R 2 s 连接的碳原子中选出的至少两个碳原子可结合形成一个缩合环）。
• US6974658B2
  申请人：——

  公开号：US6974658B2

  公开（公告）日：2005-12-13
• US6949615B2
  申请人：——

  公开号：US6949615B2

  公开（公告）日：2005-09-27