N-(4,6-dipropylnon-5-yl)perylene-3,4-dicarboxylic monoimide | 1135063-44-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: N-(4,6-dipropylnon-5-yl)perylene-3,4-dicarboxylic monoimide
• CAS: 1135063-44-3
• 化学式: C₃₇H₄₁NO₂
• 分子量: 531.738
• InChiKey: MVRAWAYXNKEYCX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.13
• 重原子数：
  40.0
• 可旋转键数：
  11.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.41
• 拓扑面积：
  37.38
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  N-(4,6-dipropylnon-5-yl)perylene-3,4-dicarboxylic monoimide 在 potassium tert-butylate 、 C.I.酸性橙108 、 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 反应 22.0h， 以23%的产率得到11,30-Bis(4,6-dipropylnonan-5-yl)-11,30-diazatridecacyclo[22.14.2.22,5.26,9.225,28.03,20.04,17.07,16.08,13.021,39.026,35.027,32.036,40]hexatetraconta-1(39),2,4,6,8,13,15,17,19,21,23,25(42),26(35),27(32),28(41),33,36(40),37,43,45-icosaene-10,12,29,31-tetrone
  参考文献：
  名称：

  Solution-Shear-Processed Quaterrylene Diimide Thin-Film Transistors Prepared by Pressure-Assisted Thermal Cleavage of Swallow Tails

  摘要：

  A scalable synthesis of swallow-tailed quaterrylene diimides (STQDIs) and a method for the solution processing of sparingly soluble quaterrylene diimide (QDI) thin films are described. The pressure-assisted thermal cleavage of swallow tails yields crystalline QDI layers with electron mobility up to 0.088 cm(2) V(-1) s(-1). The developed method opens up a new route toward the solution processing of higher rylene diimides with poor solubility.

  DOI：

  10.1021/ja110486s
• 作为产物：
  描述：

  4,6-dipropylnon-5-yl-amine 、 perylene-3,4-dicarboxylic anhydride 在 喹啉 、 zinc(II) acetate dihydrate 作用下， 反应 4.0h， 以34%的产率得到N-(4,6-dipropylnon-5-yl)perylene-3,4-dicarboxylic monoimide
  参考文献：
  名称：

  Solution-Shear-Processed Quaterrylene Diimide Thin-Film Transistors Prepared by Pressure-Assisted Thermal Cleavage of Swallow Tails

  摘要：

  A scalable synthesis of swallow-tailed quaterrylene diimides (STQDIs) and a method for the solution processing of sparingly soluble quaterrylene diimide (QDI) thin films are described. The pressure-assisted thermal cleavage of swallow tails yields crystalline QDI layers with electron mobility up to 0.088 cm(2) V(-1) s(-1). The developed method opens up a new route toward the solution processing of higher rylene diimides with poor solubility.

  DOI：

  10.1021/ja110486s