Acetic acid (2S,3R,4S,5R,6S)-2,3-diacetoxy-6-acetoxymethyl-5-((2R,3S,4R,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-ylmethyl)-tetrahydro-pyran-4-yl ester | 210637-90-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Acetic acid (2S,3R,4S,5R,6S)-2,3-diacetoxy-6-acetoxymethyl-5-((2R,3S,4R,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-ylmethyl)-tetrahydro-pyran-4-yl ester
• CAS: 210637-90-4
• 化学式: C₂₉H₄₀O₁₈
• 分子量: 676.626
• InChiKey: CKUMWDPKHGJOHM-WLIRAPOWSA-N

反应信息

• 作为反应物：
  描述：

  Acetic acid (2S,3R,4S,5R,6S)-2,3-diacetoxy-6-acetoxymethyl-5-((2R,3S,4R,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-ylmethyl)-tetrahydro-pyran-4-yl ester 在 氢氟酸 作用下， 以 吡啶 为溶剂， 反应 0.5h， 以96%的产率得到Acetic acid (2R,3R,4S,5R,6S)-3-acetoxy-6-acetoxymethyl-2-fluoro-5-((2R,3S,4R,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-ylmethyl)-tetrahydro-pyran-4-yl ester
  参考文献：
  名称：

  Transfer reactions catalyzed by cyclodextrin glucosyltransferase using 4-thiomaltosyl and C-maltosyl fluorides as artificial donors

  摘要：

  Cyclodextrin glycosyltransferase enzyme from Bacillus circulans catalyzed the effective conversion of 4-thio-alpha-maltosyl fluoride into cyclo-alpha-(1-->4)-thiomalto -tetraoside, -pentaoside, -hexaoside and linear hemithiomaltooligosaccharides. However, under the same conditions, C-maltosyl fluoride afforded only linear modified maltotetraose, maltohexaose and maltooctaose in moderate yield. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0008-6215(97)00262-0
• 作为产物：
  描述：

  乙酸酐 、 Acetic acid (2S,3R,4S,5R,6S)-3-acetoxy-6-acetoxymethyl-2-methoxy-5-((2R,3S,4R,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-ylmethyl)-tetrahydro-pyran-4-yl ester 在 硫酸 、 氢溴酸 、 silver(I) acetate 、 乙酸酐 、 溶剂黄146 作用下， 生成 Acetic acid (2S,3R,4S,5R,6S)-2,3-diacetoxy-6-acetoxymethyl-5-((2R,3S,4R,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-ylmethyl)-tetrahydro-pyran-4-yl ester
  参考文献：
  名称：

  Transfer reactions catalyzed by cyclodextrin glucosyltransferase using 4-thiomaltosyl and C-maltosyl fluorides as artificial donors

  摘要：

  Cyclodextrin glycosyltransferase enzyme from Bacillus circulans catalyzed the effective conversion of 4-thio-alpha-maltosyl fluoride into cyclo-alpha-(1-->4)-thiomalto -tetraoside, -pentaoside, -hexaoside and linear hemithiomaltooligosaccharides. However, under the same conditions, C-maltosyl fluoride afforded only linear modified maltotetraose, maltohexaose and maltooctaose in moderate yield. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0008-6215(97)00262-0