1-Hydroxy-1-vinyloxy-2-methyl-propan | 13958-24-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-Hydroxy-1-vinyloxy-2-methyl-propan
• 英文别名: 2-methyl-1-vinyloxy-propan-1-ol；isobutyraldehyde vinyl hemiacetal；1-Ethenoxy-2-methylpropan-1-ol
• CAS: 13958-24-2
• 化学式: C₆H₁₂O₂
• 分子量: 116.16
• InChiKey: LNTDXONIQLFHFG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  8
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-methyl-1,1-bis-vinyloxy-propane 在 mercury(II) diacetate 、 mercury(II) oxide 作用下， 以 乙醇 为溶剂， 生成 1-Hydroxy-1-vinyloxy-2-methyl-propan
  参考文献：
  名称：

  Veretenova,T.N.; Balin,A.I., Journal of general chemistry of the USSR, 1966, vol. 36, p. 2013 - 2014

  摘要：

  DOI：

文献信息

• [EN] PRODUCTION METHOD OF FLUOROETHERCARBOXYLIC ACID FLUORIDE AND FLUOROETHERCARBOXYLIC ACID<br/>[FR] PROCÉDÉ DE PRODUCTION DE FLUORURE D'ACIDE FLUOROÉTHERCARBOXYLIQUE ET D'ACIDE FLUOROÉTHERCARBOXYLIQUE
  申请人：DAIKIN IND LTD

  公开号：WO2010038902A1

  公开（公告）日：2010-04-08

  The present invention is a production method of a fluoroethercarboxylic acid fluoride, comprising the step of selectively producing a fluoroethercarboxylic acid fluoride represented by the formula (I): CF3O(CF(CF3)CF2O)CF(CF3)COF (I) by reacting hexafluoropropylene oxide with carbonyl fluoride in a solvent at a temperature of -30 to 40 °C in the presence of a catalyst, wherein the catalyst comprises at least one species selected from the group consisting of metal fluorides, tertiary amines, tertiary diamines and tetraalkylammonium salts, and the solvent is an aprotic polar solvent.

  本发明是一种氟醚羧酸氟的生产方法，包括以下步骤：在溶剂中，在催化剂的存在下，通过反应六氟丙烷氧化物和羰基氟，以选择性地生产由式(I)表示的氟醚羧酸氟：CF3O(CF(CF3)CF2O)CF( )COF (I)。其中，催化剂包括金属氟化物、三级胺、三级二胺和四烷基铵盐中至少一种物种，溶剂为无水极性溶剂，反应温度在-30到40°C之间。
• Fluoroalkyl carboxylic acid derivative, method for producing fluorine-containing polymer, and aqueous dispersion of fluorine-containing polymer
  申请人：Morita Shigeru

  公开号：US20060281946A1

  公开（公告）日：2006-12-14

  This invention provides a novel compound which can be properly used as a surfactant, a method of producing a fluoropolymer, surfactant and a fluoropolymer aqueous dispersions using the novel compound. This invention is a fluoroalkylcarboxylic acid derivative which is represented by the general formula (i): Rf 1 (OCH 2 CF 2 CF 2 ) n1 OCX 1 X 2 CF 2 (Rf 2 ) n2 COOM   (i) wherein Rf 1 represents a straight or branched fluoroalkyl group containing 1 to 20 carbon atoms, which fluoroalkyl group may optionally contain 1 to 5 oxygen atoms in the principal chain thereof, Rf 2 represents a straight or branched fluoroalkylene group containing 1 to 25 carbon atoms, said fluoroalkylene group may optionally contain 1 to 5 oxygen atoms in the principal chain thereof, n1 represents an integer of 0 to 3, n2 represents an integer of 0 or 1, X 1 and X 2 are the same or different and each represents hydrogen atom or fluorine atom, and M represents NH 4 or a monovalent metal element.

  该发明提供了一种新型化合物，可适当用作表面活性剂，一种生产氟聚合物的方法，使用该新型化合物制备表面活性剂和氟聚合物水分散液。该发明是一种氟烷基羧酸衍生物，由通式（i）表示：Rf1（OCH2CF2CF2）n1OCX1X2CF2（Rf2）n2COOM   （i）其中，Rf1表示含有1到20个碳原子的直链或支链氟烷基，该氟烷基在其主链中可以选择性地含有1到5个氧原子，Rf2表示含有1到25个碳原子的直链或支链氟烷基，该氟烷基在其主链中可以选择性地含有1到5个氧原子，n1表示0到3的整数，n2表示0或1的整数，X1和X2相同或不同，每个表示氢原子或氟原子，M表示NH4或一价金属元素。
• FLUOROALKYL CARBOXYLIC ACID DERIVATIVE, METHOD FOR PRODUCING FLUORINE-CONTAINING POLYMER, AND AQUEOUS DISPERSION OF FLUORINE-CONTAINING POLYMER
  申请人：MORITA Shigeru

  公开号：US20090298984A1

  公开（公告）日：2009-12-03

  This invention provides a novel compound which can be properly used as a surfactant, a method of producing a fluoropolymer, surfactant and a fluoropolymer aqueous dispersions using the novel compound. This invention is a fluoroalkylcarboxylic acid derivative which is represented by the general formula (i): Rf 1 (OCH 2 CF 2 CF 2 ) n1 OCX 1 X 2 CF 2 (Rf 2 ) n2 COOM  (i) wherein Rf 1 represents a straight or branched fluoroalkyl group containing 1 to 20 carbon atoms, which fluoroalkyl group may optionally contain 1 to 5 oxygen atoms in the principal chain thereof, Rf 2 represents a straight or branched fluoroalkylene group containing 1 to 25 carbon atoms, said fluoroalkylene group may optionally contain 1 to 5 oxygen atoms in the principal chain thereof, n1 represents an integer of 0 to 3, n2 represents an integer of 0 or 1, X 1 and X 2 are the same or different and each represents hydrogen atom or fluorine atom, and M represents NH 4 or a monovalent metal element.

  本发明提供了一种新型化合物，可适当用作表面活性剂，生产氟聚合物的方法，使用新型化合物制备的表面活性剂和氟聚合物水分散体。本发明是一种氟烷基羧酸衍生物，其由通式（i）表示：Rf1（OCH2CF2CF2）n1OCX1X2CF2（Rf2）n2COOM（i）其中，Rf1表示含有1至20个碳原子的直链或支链氟烷基，该氟烷基在其主链中可以选择性地含有1至5个氧原子；Rf2表示含有1至25个碳原子的直链或支链氟烷基烯基，该氟烷基烯基在其主链中可以选择性地含有1至5个氧原子；n1表示0至3的整数，n2表示0或1的整数，X1和X2相同或不同，分别表示氢原子或氟原子，M表示NH4或一价金属元素。
• NOVEL COMPOUND, METHOD FOR PRODUCING THE SAME AND METHOD FOR PRODUCING FLUOROPOLYMER
  申请人：Tsuda Nobuhiko

  公开号：US20100197852A1

  公开（公告）日：2010-08-05

  The invention provides a compound which is useful in production of a fluoropolymer and easy to be removed from the produced fluoropolymer, a method of producing the compound, and a method of producing a fluoropolymer using the compound. The invention provides a compound which is represented by Rf 1 —CH 2 O—CF 2 —CHF—Rf 2 —X, wherein Rf 1 represents a fluoroalkyl group containing 1 to 5 carbon atoms, Rf 2 represents a fluoroalkylene group containing 1 to 3 carbon atoms, X represents —COOM or —SO 3 M, and M represents one of H, K, Na, and NH 4 .

  本发明提供了一种化合物，该化合物在制备氟聚合物时非常有用，并且易于从制得的氟聚合物中去除，同时还提供了一种制备该化合物的方法以及使用该化合物制备氟聚合物的方法。该化合物由Rf1-CH2O-CF2-CHF-Rf2-X表示，其中Rf1表示含有1至5个碳原子的氟烷基，Rf2表示含有1至3个碳原子的氟烷基，X表示-COOM或-SO3M，M表示H、K、Na或NH4中的一种。
• METHOD FOR PRODUCING HOMOPOLYMER OR RANDOM COPOLYMER OF HYDROXYL GROUP-CONTAINING VINYL ETHER
  申请人：MARUZEN PETROCHEMICAL CO., LTD.

  公开号：US20150005467A1

  公开（公告）日：2015-01-01

  [Object] To provide a method of producing a homopolymer or random copolymer of hydroxyl group-containing vinyl ether simply and conveniently as well as efficiently. [Means for solving problem] A method of producing a homopolymer or random copolymer of hydroxyl group-containing vinyl ether according to the present invention comprises the step of polymerizing a monomer component comprising at least one hydroxyl group-containing vinyl ether using an oil-soluble radical polymerization initiator in the absence or presence of a solvent.

  【目标】提供一种简单、方便和高效的生产含羟基乙烯醚同聚物或随机共聚物的方法。 【解决问题的方法】根据本发明，生产含羟基乙烯醚同聚物或随机共聚物的方法包括以下步骤：使用油溶性自由基聚合引发剂，在有机溶剂存在或不存在的情况下，聚合至少含有一种羟基乙烯醚单体组分。