| 189363-01-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 189363-01-7
• 化学式: C₂₆H₂₈CuF₆N₂O₄
• 分子量: 610.056
• InChiKey: HIPSFCCJMKFGLR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,1,1-三氟-5,5-二甲基-2,4-己二酮 以 水 、 苯 为溶剂， 生成
  参考文献：
  名称：

  Crystal structure of copper(II) pivaloyltrifluoracetonate adducts with o-phenanthroline and 2,2′-dipyridyl

  摘要：

  The crystal structure of Cu(pta)(2) . Phen has been determined. The phenanthroline ligand occupies a position in the equatorial plane of the tetragonally distorted octahedron with equal Cu-N distances and equivalent beta-diketonate-anions. Cu(pta)(2) . 2,2'-Dipy is isostructural to Cu(pta)(2) . Phen. The volatility of adducts decreases in the sequence Cu(thd)(2) . Phen, Cu(pta(2)). Phen and Cu(hfa)(2) . Phen changing inversely to that of the beta-diketonates. The variation of packing mode caused by the difference of the molecular structure is considered to be responsible for the effect. The changes of the electronic spectra of copper(II) beta-diketonates caused by adduct formation are discussed. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00519-0