| 1209004-29-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• CAS: 1209004-29-4
• 化学式: C₁₅H₁₅NO₂
• 分子量: 241.29
• InChiKey: DBPRSNHWRMXCTI-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  、 丙二酸二乙酯 在 sodium ethanolate 作用下， 反应 0.04h， 以83%的产率得到ethyl (E)-3-[5-(ethyl)-2-hydroxyphenylanilino]-2-propenoate
  参考文献：
  名称：

  Novel Rearrangement During the Reaction of Diethylmalonate with α-(5-Substituted 2-hydroxyphenyl)-N-phenyl Nitrones

  摘要：

  The hydroxyl group at the ortho position of the -aryl ring of -(2-hydroxyaryl)-N-aryl nitrones altered the expected course of the reaction between differently substituted -(2-hydroxyaryl)-N-aryl nitrones and diethylmalonate, leading to the formation of an enamine involving an interesting rearrangement under microwave irradiation. The enamines have been characterized by NMR and x-ray analyses, and a reasonable mechanism has been put forwarded to explain the rearrangement.

  DOI：

  10.1080/00397910902985481