1-(6,7,10,11-Tetrakis-decoxy-3-methoxytriphenylen-2-yl)imidazole | 1246534-70-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 1-(6,7,10,11-Tetrakis-decoxy-3-methoxytriphenylen-2-yl)imidazole
• 英文别名: 1-(6,7,10,11-tetrakis-decoxy-3-methoxytriphenylen-2-yl)imidazole
• CAS: 1246534-70-2
• 化学式: C₆₂H₉₆N₂O₅
• 分子量: 949.455
• InChiKey: SUSWKFSDDCHKHZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  22.5
• 重原子数：
  69
• 可旋转键数：
  42
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.66
• 拓扑面积：
  64
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  咪唑 、 2-bromo-6,7,10,11-tetra(decyloxy)-3-methoxytriphenylene 在 copper(I) oxide 、 4,7-二甲氧基-1,10-菲咯啉 、 caesium carbonate 、 copper(II) oxide 作用下， 以 N-甲基吡咯烷酮 、 甲醇 、 二氯甲烷 为溶剂， 反应 56.0h， 以75%的产率得到1-(6,7,10,11-Tetrakis-decoxy-3-methoxytriphenylen-2-yl)imidazole
  参考文献：
  名称：

  Self-Assembled Helical Nanofibers Made of Achiral Molecular Disks Having Molecular Adapter

  摘要：

  An achiral disk-shaped molecule (2) having one imidazole unit was found to be assembled into long and twisted nanoscopic fibers having 10 - 100 nm width as shown by transmission electron microscopy (TEM) and atomic force microscope (AFM). Compound 2 leads to spontaneous chiral symmetry breaking through the steric effect of imidazole units during the formation of one-dimensional stacks. The imidazole in 2 acts as a molecular adaptor to form hydrogen bonds and accumulate metal ions. The supramolecular connection of 2 with benzene-1,3,5-tricarboxylic acid through the hydrogen bonds exhibited a thermotropic liquid crystalline properties. Silver nanopartidies were deposited onto the self-assembled nanofibers by the photoreduction of silver ions.

  DOI：

  10.1021/cm102276a