| 229022-39-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 229022-39-3
• 化学式: C₁₆H₁₅NO₃Pd
• 分子量: 375.72
• InChiKey: FYSIOQADJPUBRU-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  、 乙酰丙酮 在 sodium methoxide 作用下， 以 甲醇 为溶剂， 以43%的产率得到
  参考文献：
  名称：

  Cyclometallated compounds. XIII. Cyclopalladation of 2-phenoxypyridine and structurally-related compounds

  摘要：

  2-Phenoxypyridine and 2-phenylsulfanylpyridine are cyclopalladated readily by palladium acetate to give six-membered metallocycles. Extension to the three isomeric bis(2-pyridyloxy)benzenes leads to a new series of doubly-cyclopalladated compounds. In contrast, 3-6-diphenoxypyridazine and 4-6-diphenoxypyrimidine only undergo monopalladation, whilst their sulfur analogues are resistant to cyclopalladation. All cyclometallated compounds are converted to their acetylacetonate derivatives and the X-ray crystal structure of one of these is described. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)01203-0