[Zn2(N,N,N′,N′-tetrakis(1-isoquinolylmethyl)-2-hydroxy-1,3-propanediamine)(P1P2-diphenylpyrophosphate)](perchlorate) | 1453273-97-6

• 英文名称: [Zn2(N,N,N′,N′-tetrakis(1-isoquinolylmethyl)-2-hydroxy-1,3-propanediamine)(P1P2-diphenylpyrophosphate)](perchlorate)
• 英文别名: [Zn₂(N,N,N′,N′-tetrakis(1-isoquinolylmethyl)-2-hydroxy-1,3-propanediamine)(P¹P²-diphenylpyrophosphate)](perchlorate)
• CAS: 1453273-97-6
• 化学式: C₅₅H₄₇N₆O₈P₂Zn₂*ClO₄
• 分子量: 1212.19
• InChiKey: LXHGDVDXEYFLND-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  zinc perchlorate 、 disodium P¹P²-diphenylpyrophosphate 、 N,N,N’,N’-tetrakis(1-isoquinolylmethyl)-2-hydroxy-1,3-propanediamine 以 四氢呋喃 、 水 为溶剂， 以45%的产率得到[Zn2(N,N,N′,N′-tetrakis(1-isoquinolylmethyl)-2-hydroxy-1,3-propanediamine)(P1P2-diphenylpyrophosphate)](perchlorate)
  参考文献：
  名称：

  Quantitative Fluorescent Detection of Pyrophosphate with Quinoline-Ligated Dinuclear Zinc Complexes

  摘要：

  Dinuclear zinc complex [Zn-2(TQHPN)-(AcO)](2+) exhibits characteristic fluorescence response (lambda(ex) = 317 nm and lambda(em) = 455 nm) toward pyrophosphate (PPi) with maximum fluorescence upon 1:1 Zn-2(TQHPN)-PPi complex formation. The crystallographic investigation utilizing (PP2)-P-1-Ph(2)PPi revealed that the fluorescent response mechanism is due to intramolecular excimer formation of two quinoline rings.

  DOI：

  10.1021/ic401605m