(Z)-3,6-bis[2-(pinacolboryl)vinyl]-9-hexylcarbazole | 779357-45-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: (Z)-3,6-bis[2-(pinacolboryl)vinyl]-9-hexylcarbazole
• 英文别名: 9-hexyl-3,6-bis[(Z)-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)ethenyl]carbazole
• CAS: 779357-45-8
• 化学式: C₃₄H₄₇B₂NO₄
• 分子量: 555.373
• InChiKey: COIIIOAJVYBUOS-AUYXYSRISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.66
• 重原子数：
  41
• 可旋转键数：
  9
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  41.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  3,6-diethynyl-9-hexyl-9H-carbazole 、 频那醇硼烷 在 三乙胺 作用下， 以 环己烷 为溶剂， 生成 (Z)-3,6-bis[2-(pinacolboryl)vinyl]-9-hexylcarbazole 、 (E)-3,6-bis[2-(pinacolboryl)vinyl]-9-hexylcarbazole
  参考文献：
  名称：

  Stereoselective Hydroboration of Diynes and Triyne to Give Products Containing Multiple Vinylene Bridges:  A Versatile Application to Fluorescent Dyes and Light-Emitting Copolymers

  摘要：

  The Rh(I)-catalyzed hydroboration of a variety of aromatic diynes and a triyne afforded bis(boryl)- and tris(boryl)vinyl products. The hydroboration products under-went Suzuki cross-coupling reactions with a variety of substrates containing chromophore units to give fluorescent dye-substituted products. The hydroboration product also reacted with dibromoarenes to afford an oligomer with a vinylene unit along the oligomer backbone.

  DOI：

  10.1021/om049832m

文献信息

• Stereoselective Hydroboration of Diynes and Triyne to Give Products Containing Multiple Vinylene Bridges:  A Versatile Application to Fluorescent Dyes and Light-Emitting Copolymers
  作者：Taegweon Lee、Chul Baik、Il Jung、Kyu Ho Song、Sanghoon Kim、Duckhyun Kim、Sang Ook Kang、Jaejung Ko

  DOI：10.1021/om049832m

  日期：2004.9.1

  The Rh(I)-catalyzed hydroboration of a variety of aromatic diynes and a triyne afforded bis(boryl)- and tris(boryl)vinyl products. The hydroboration products under-went Suzuki cross-coupling reactions with a variety of substrates containing chromophore units to give fluorescent dye-substituted products. The hydroboration product also reacted with dibromoarenes to afford an oligomer with a vinylene unit along the oligomer backbone.