| 357194-60-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 357194-60-6
• 化学式: C₂₃H₄₀CoN₄O₂S₂*Na
• 分子量: 550.711
• InChiKey: HYGHXOGHCDVATN-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  、 异氰酸叔丁酯 以 丙酮 为溶剂， 以99%的产率得到
  参考文献：
  名称：

  A square-planar di-N-carboxamido, dithiolato–cobalt(III) complex related to nitrile hydratase metallic site. Addition of axial ligands and EXAFS study of the derived dicyano and diisocyanido complexes

  摘要：

  A square-planar cobalt(III) complex with a N2S2 di-N-carboxamido di-thiolato tetradentate ligand, mimics the metal core of the cobalt containing nitrile hydratases. It forms hexacoordinated complexes only upon addition of ligands like cyanide or isocyanides. An EXAFS analysis confirmed that two axial ligands get bound, and lead to a significant increase of the bond lengths between the cobalt(III) and the equatorial ligands. Whereas the planar complex is stable in the presence of air or hydrogen peroxide, its hexacoordinated derivatives with strong sigma -donor axial ligands undergo an oxygenation of the equatorial thiolate ligands. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00413-3