1,2-Dideuteriopropane | 20717-77-5

• 分子结构分类: 有机化合物 - 碳氢化合物 - 饱和烃
• 英文名称: 1,2-Dideuteriopropane
• 英文别名: 1,2-dideuteriopropane
• CAS: 20717-77-5
• 化学式: C₃H₈
• 分子量: 46.0806
• InChiKey: ATUOYWHBWRKTHZ-SDTNDFKLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  三聚丙烯 在 platinum on silica 氘 作用下， 生成 1,2-Dideuteriopropane
  参考文献：
  名称：

  Study on d state of platinum in platinum/silica and sodium/platinum/silica catalysts under C:C hydrogenation conditions by x-ray absorption near-edge structure spectroscopy

  摘要：

  The change in the d-electron density of platinum during D2 + CH2 = CHX reactions on Pt/SiO2 and Na/Pt/SiO2 catalysts and its influence on the catalysis were studied by X-ray absorption near-edge structure (XANES) spectroscopy, kinetics and FT-IR. It was demonstrated from the change of the white lines in XANES spectra at Pt L2 and L3 edges that CH2 = CHX (X = H, CH3, COCH3, CF3, and CN) is adsorbed on the Pt surface and extracts the electrons of the d state. Hence, the deuterogenation rate is reduced as the value of Hammett's sigma-P increases. The linear free energy relationship between the reaction rate and sigma-P was observed for the deuterogenation of CH2 = CHX. The rate of ethene deuterogenation was promoted by Na2O addition. The electron density of unoccupied d states of Pt under vacuum decreased by Na2O addition, indicating the electron donation from Na2O to Pt particles. However, most of these additional electrons were observed to move to ethene under reaction conditions. The acceptor of the electrons was suggested to be di-sigma-ethene by the shift of nu-(C-H). The kinetic parameters are discussed in relation to the change in the d state of Pt as a function of sigma-P and Na quantity.

  DOI：

  10.1021/j100172a048

文献信息

• Reactions of cyclopropane and deuterium over supported metal catalysts
  作者：Ronald Brown、Charles Kemball

  DOI：10.1039/ft9908603815

  日期：——

  The reaction of cyclopropane and deuterium has been studied at low temperatures over a number of supported metal catalysts. The main reaction was normally ring-opening, yielding a mixture of isotopic propanes which were analysed mass-spectrometrically and by deuterium NMR spectroscopy. The patterns of isotopic propanes varied substantially with the nature of the metal and provided information about

  已经在低温下在多种负载的金属催化剂上研究了环丙烷和氘的反应。主要反应通常是开环，生成同位素丙烷的混合物，将其进行质谱分析和氘核NMR光谱分析。同位素丙烷的模式随金属的性质而变化，并提供了有关反应机理中所吸附的中间体类型的信息。
• Reactions of 2-methylpropene and other alkenes on zinc oxide
  作者：Ronald Brown、Charles Kemball、Duncan Taylor

  DOI：10.1039/f19837902899

  日期：——

  Studies have been made on the hydrogenation, deuteration and exchange with deuterium of ethene, propene and 2-methylpropene on zinc oxide and Arrhenius parameters for the reactions have been determined. Some general conclusions are reached about the catalytic behaviour of alkenes on zinc oxide from these and earlier results.

  已经研究了在氧化锌上的乙烯，丙烯和2-甲基丙烯的氘的氢化，氘化和与氘的交换，并且确定了用于反应的Arrhenius参数。从这些和较早的结果可以得出关于烯烃在氧化锌上的催化行为的一些一般性结论。
• Study on d state of platinum in platinum/silica and sodium/platinum/silica catalysts under C:C hydrogenation conditions by x-ray absorption near-edge structure spectroscopy
  作者：Hideaki Yoshitake、Yasuhiro Iwasawa

  DOI：10.1021/j100172a048

  日期：1991.9

  The change in the d-electron density of platinum during D2 + CH2 = CHX reactions on Pt/SiO2 and Na/Pt/SiO2 catalysts and its influence on the catalysis were studied by X-ray absorption near-edge structure (XANES) spectroscopy, kinetics and FT-IR. It was demonstrated from the change of the white lines in XANES spectra at Pt L2 and L3 edges that CH2 = CHX (X = H, CH3, COCH3, CF3, and CN) is adsorbed on the Pt surface and extracts the electrons of the d state. Hence, the deuterogenation rate is reduced as the value of Hammett's sigma-P increases. The linear free energy relationship between the reaction rate and sigma-P was observed for the deuterogenation of CH2 = CHX. The rate of ethene deuterogenation was promoted by Na2O addition. The electron density of unoccupied d states of Pt under vacuum decreased by Na2O addition, indicating the electron donation from Na2O to Pt particles. However, most of these additional electrons were observed to move to ethene under reaction conditions. The acceptor of the electrons was suggested to be di-sigma-ethene by the shift of nu-(C-H). The kinetic parameters are discussed in relation to the change in the d state of Pt as a function of sigma-P and Na quantity.