2-(4-Bromo-2,3,5,6-tetramethylphenyl)-3-[4-[2-(4-bromo-2,3,5,6-tetramethylphenyl)-9-(2,4,6-trimethylphenyl)-1,10-phenanthrolin-3-yl]buta-1,3-diynyl]-9-(2,4,6-trimethylphenyl)-1,10-phenanthroline | 856659-02-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 2-(4-Bromo-2,3,5,6-tetramethylphenyl)-3-[4-[2-(4-bromo-2,3,5,6-tetramethylphenyl)-9-(2,4,6-trimethylphenyl)-1,10-phenanthrolin-3-yl]buta-1,3-diynyl]-9-(2,4,6-trimethylphenyl)-1,10-phenanthroline
• 英文别名: 2-(4-bromo-2,3,5,6-tetramethylphenyl)-3-[4-[2-(4-bromo-2,3,5,6-tetramethylphenyl)-9-(2,4,6-trimethylphenyl)-1,10-phenanthrolin-3-yl]buta-1,3-diynyl]-9-(2,4,6-trimethylphenyl)-1,10-phenanthroline
• CAS: 856659-02-4
• 化学式: C₆₆H₅₆Br₂N₄
• 分子量: 1065.01
• InChiKey: BVPYULLDMKDYEH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  18.5
• 重原子数：
  72
• 可旋转键数：
  7
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  锌 、 、 2-(4-Bromo-2,3,5,6-tetramethylphenyl)-3-[4-[2-(4-bromo-2,3,5,6-tetramethylphenyl)-9-(2,4,6-trimethylphenyl)-1,10-phenanthrolin-3-yl]buta-1,3-diynyl]-9-(2,4,6-trimethylphenyl)-1,10-phenanthroline 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Multicomponent Assembly of Heterometallic Isosceles Triangles

  摘要：

  The multicomponent synthesis and solution-state characterization of three supramolecular bis-heterometallic isosceles triangles are elaborated. The triangular assemblies are isosceles both geometrically and chemically; they comprise multiple ligands, metals, and binding motifs. Variation of the length of one side of the triangle by changing the number of phenyl spacers n = 0, 1, and 2 influences the redox potential of the opposing copper(I) center, allowing translation of the nanomechanical changes into electronically readable values.

  DOI：

  10.1021/ic8021084

文献信息

• Multicomponent Assembly of Heterometallic Isosceles Triangles
  作者：Michael Schmittel、Kingsuk Mahata

  DOI：10.1021/ic8021084

  日期：2009.2.2

  The multicomponent synthesis and solution-state characterization of three supramolecular bis-heterometallic isosceles triangles are elaborated. The triangular assemblies are isosceles both geometrically and chemically; they comprise multiple ligands, metals, and binding motifs. Variation of the length of one side of the triangle by changing the number of phenyl spacers n = 0, 1, and 2 influences the redox potential of the opposing copper(I) center, allowing translation of the nanomechanical changes into electronically readable values.