(R)-6-Furan-3-yl-3-methyl-dihydro-pyran-2,4-dione | 255870-29-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 内酯类
• 英文名称: (R)-6-Furan-3-yl-3-methyl-dihydro-pyran-2,4-dione
• CAS: 255870-29-2
• 化学式: C₁₀H₁₀O₄
• 分子量: 194.187
• InChiKey: YAJMIARFZFPRMC-IOJJLOCKSA-N

反应信息

• 作为反应物：
  描述：

  (R)-6-Furan-3-yl-3-methyl-dihydro-pyran-2,4-dione 在 硼烷铵络合物 作用下， 以 四氢呋喃 为溶剂， 生成 (R)-6-Furan-3-yl-4-hydroxy-3-methyl-tetrahydro-pyran-2-one
  参考文献：
  名称：

  Efficient synthesis of chiral non-racemic 6-(furan-3-yl)-5,6-dihydro-pyran-2-ones

  摘要：

  The title compounds are accessible in high yields and enantioselectivities by a five-step sequence involving in the key-step asymmetric aldol condensations of masked acetoacetic esters to 3-formyl furan. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0957-4166(99)00396-1
• 作为产物：
  描述：

  6-(2-furan-3-yl-2-hydroxy-ethyl)-2,2,5-trimethyl[1,3]dioxin-4-one 在 potassium carbonate 作用下， 以 甲醇 为溶剂， 生成 (R)-6-Furan-3-yl-3-methyl-dihydro-pyran-2,4-dione
  参考文献：
  名称：

  Efficient synthesis of chiral non-racemic 6-(furan-3-yl)-5,6-dihydro-pyran-2-ones

  摘要：

  The title compounds are accessible in high yields and enantioselectivities by a five-step sequence involving in the key-step asymmetric aldol condensations of masked acetoacetic esters to 3-formyl furan. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0957-4166(99)00396-1