(1S*,5S*,8aR*,10aR*)-1-<(4a'R*,8'S*,8a'R*)-8',8a'-dimethyl-4'-oxo-1',4',4a',5',6',7',8',8a'-octahydronaphthalen-2'-yl>-4-hydroxy-1,4,5,10a-tetramethyl-1,2,3,4,5,6,7,9,8,8a,10,10a-dodecahydroanthracen-9-one | 83117-27-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (1S*,5S*,8aR*,10aR*)-1-<(4a'R*,8'S*,8a'R*)-8',8a'-dimethyl-4'-oxo-1',4',4a',5',6',7',8',8a'-octahydronaphthalen-2'-yl>-4-hydroxy-1,4,5,10a-tetramethyl-1,2,3,4,5,6,7,9,8,8a,10,10a-dodecahydroanthracen-9-one
• CAS: 83117-27-5
• 化学式: C₃₀H₄₄O₃
• 分子量: 452.678
• InChiKey: CTYXNVZKYXCJNW-UBQNILRVSA-N

反应信息

• 作为反应物：
  描述：

  (1S*,5S*,8aR*,10aR*)-1-<(4a'R*,8'S*,8a'R*)-8',8a'-dimethyl-4'-oxo-1',4',4a',5',6',7',8',8a'-octahydronaphthalen-2'-yl>-4-hydroxy-1,4,5,10a-tetramethyl-1,2,3,4,5,6,7,9,8,8a,10,10a-dodecahydroanthracen-9-one 、 乙酰氯 在 N,N-二甲基苯胺 作用下， 以 氯仿 为溶剂， 反应 70.0h， 以61%的产率得到(1S*,5S*,8aR*,10aR*)-4-acetoxy-1-<(8'S*,8a'R*)-4'-acetoxy-8',8a'-dimethyl-4'-oxo-1',5',6',7',8',8a'-hexahydronaphthalen-2'-yl>-4-hydroxy-1,4,5,10a-tetramethyl-1,2,3,4,5,6,7,9,8,8a,10,10a-dodecahydroanthracen-9-one
  参考文献：
  名称：

  Lewis, David E.; Massy-Westropp, Ralph A.; Ingham, Colin F., Australian Journal of Chemistry, 1982, vol. 35, # 4, p. 809 - 826

  摘要：

  DOI：
• 作为产物：
  描述：

  (1S*,5S*,10aR*)-1-<(8'S*,8a'R*)-8',8a'-dimethyl-4'-oxo-1',4',6',7',8',8a'-hexahydronaphthalen-2'-yl>-4-hydroxy-1,4,5,10a-tetramethyl-1,2,3,4,5,6,7,9,10,10a-decahydroanthracen-9-one 在 sodium tetrahydroborate 作用下， 以 乙酸乙酯 为溶剂， 反应 24.0h， 生成 (1S*,5S*,8aR*,10aR*)-1-<(4a'R*,8'S*,8a'R*)-8',8a'-dimethyl-4'-oxo-1',4',4a',5',6',7',8',8a'-octahydronaphthalen-2'-yl>-4-hydroxy-1,4,5,10a-tetramethyl-1,2,3,4,5,6,7,9,8,8a,10,10a-dodecahydroanthracen-9-one
  参考文献：
  名称：

  Lewis, David E.; Massy-Westropp, Ralph A.; Ingham, Colin F., Australian Journal of Chemistry, 1982, vol. 35, # 4, p. 809 - 826

  摘要：

  DOI：