[(dimethoxyethane) hafnium (diethylamide)2 (methyl)2] | 1035459-57-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [(dimethoxyethane) hafnium (diethylamide)2 (methyl)2]
• CAS: 1035459-57-4
• 化学式: C₁₄H₃₆HfN₂O₂
• 分子量: 442.942
• InChiKey: RQSPKLCMUVPXTP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [(dimethoxyethane) hafnium (diethylamide)2 (methyl)2] 、 异丙醇 以 乙醚 为溶剂， 生成 [hafnium (isopropoxy)2 (diethylamide)2]
  参考文献：
  名称：

  Synthesis and physico-chemical characterization of [Hf(NEt2)2Cl2(DME)] and its use as catalyst for ethylene polymerization

  摘要：

  The new solid-state complex {[Hf(NEt2)(2)Cl-2(DME)] (DME = 1,2-dimethoxyethane) 1, intermediate in the synthesis of the new bisdiethylamide bis-isopropoxy hafnium (IV) complex [Hf(NEt2)(2)(O'Pr)(2)], has been synthesized, isolated and characterized by NMR spectroscopy and X-ray diffraction. The crystal structure showed the metal to be hexa-coordinated with a distorted octahedral geometry. Catalytic tests for the polymerization of ethylene have been carried out using this intermediate with [(NHMe2Ph)B(C6F5)(4)] as cocatalyst. The obtained polymer had a high molecular weight and a high melting point, characteristic of a high density polyethylene (HDPE). (c) 2007 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.inoche.2007.05.002
• 作为产物：
  描述：

  cis-N,trans-Cl-[(dimethoxyethane) hafnium (diethylamide)2(chloride)2] 、 甲基锂 在 butyllithium 作用下， 以 乙醚 为溶剂， 生成 [(dimethoxyethane) hafnium (diethylamide)2 (methyl)2]
  参考文献：
  名称：

  Synthesis and physico-chemical characterization of [Hf(NEt2)2Cl2(DME)] and its use as catalyst for ethylene polymerization

  摘要：

  The new solid-state complex {[Hf(NEt2)(2)Cl-2(DME)] (DME = 1,2-dimethoxyethane) 1, intermediate in the synthesis of the new bisdiethylamide bis-isopropoxy hafnium (IV) complex [Hf(NEt2)(2)(O'Pr)(2)], has been synthesized, isolated and characterized by NMR spectroscopy and X-ray diffraction. The crystal structure showed the metal to be hexa-coordinated with a distorted octahedral geometry. Catalytic tests for the polymerization of ethylene have been carried out using this intermediate with [(NHMe2Ph)B(C6F5)(4)] as cocatalyst. The obtained polymer had a high molecular weight and a high melting point, characteristic of a high density polyethylene (HDPE). (c) 2007 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.inoche.2007.05.002