(2-oxo-naphthalene-formyl)[(1-formyl)naphtholato(O,O)]bis(trimethylphosphine)cobalt(III) | 1018071-03-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (2-oxo-naphthalene-formyl)[(1-formyl)naphtholato(O,O)]bis(trimethylphosphine)cobalt(III)
• CAS: 1018071-03-8
• 化学式: C₂₈H₃₁CoO₄P₂
• 分子量: 552.492
• InChiKey: JIOOOJVQKVFXKI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  mer-hydrido-(2-oxo-1-naphthoyl)tris(trimethylphosphane)cobalt(III) 、 2-(二苯基膦基)苯硫酚 以 乙醚 为溶剂， 以33%的产率得到(2-oxo-naphthalene-formyl)[(1-formyl)naphtholato(O,O)]bis(trimethylphosphine)cobalt(III)
  参考文献：
  名称：

  Reaction of acyl(hydrido)cobalt(III) complexes with (2-diphenylphosphanyl)thiophenol and the influence of chelating ligands containing hard/soft donor atoms on the stability of cobalt complexes

  摘要：

  The reaction of acyl(hydrido)cobalt(III) complexes Co-III (O boolean AND C=O)(H)(PMe3)(3) (1-5) with (2-diphenylphosphanyl)thiophenol afforded four types of complexes Co-III (O boolean AND C=O)(P boolean AND S)(PMe3)(2) (6-7), Co-III (O boolean AND C=O)(O boolean AND OHC)(2) (11-15), Co-III (P boolean AND S)(PMe3)(3) (16), and Co-II (P boolean AND S-2)(PMe3) (17). A mechanism for the formation of these complexes is proposed. The influences of chelating ligands containing hard/soft donor atoms on the stability of the cobalt complexes in different oxidation states are discussed with respect to the HSAB concept. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.11.010