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N,N'-bis(3-pentyl)-2,5,8,11-tetrakis{2-[tris(trimethylsiloxy)silyl]-ethyl}perylene-3,4:9,10-tetracarboxylic acid bisimide | 1360456-99-0

中文名称
——
中文别名
——
英文名称
N,N'-bis(3-pentyl)-2,5,8,11-tetrakis{2-[tris(trimethylsiloxy)silyl]-ethyl}perylene-3,4:9,10-tetracarboxylic acid bisimide
英文别名
7,18-Di(pentan-3-yl)-10,15,21,25-tetrakis[2-tris(trimethylsilyloxy)silylethyl]-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone;7,18-di(pentan-3-yl)-10,15,21,25-tetrakis[2-tris(trimethylsilyloxy)silylethyl]-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone
N,N'-bis(3-pentyl)-2,5,8,11-tetrakis{2-[tris(trimethylsiloxy)silyl]-ethyl}perylene-3,4:9,10-tetracarboxylic acid bisimide化学式
CAS
1360456-99-0
化学式
C78H150N2O16Si16
mdl
——
分子量
1821.42
InChiKey
AIMKOMVOMZBASH-UHFFFAOYSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

计算性质

  • 辛醇/水分配系数(LogP):
    23.45
  • 重原子数:
    112
  • 可旋转键数:
    42
  • 环数:
    7.0
  • sp3杂化的碳原子比例:
    0.69
  • 拓扑面积:
    186
  • 氢给体数:
    0
  • 氢受体数:
    16

上下游信息

  • 上游原料
    中文名称 英文名称 CAS号 化学式 分子量

反应信息

  • 作为产物:
    描述:
    乙烯基三(三甲基硅氧烷基)硅烷2,9-二(3-戊烷基)异喹啉并[4',5',6':6,5,10]蒽并[2,1,9-def]异喹啉-1,3,8,10(2H,9H)-四酮RuH2(CO)(PPh3)3均三甲苯 作用下, 反应 48.0h, 以37%的产率得到N,N'-bis(3-pentyl)-2,5,8,11-tetrakis{2-[tris(trimethylsiloxy)silyl]-ethyl}perylene-3,4:9,10-tetracarboxylic acid bisimide
    参考文献:
    名称:
    变色Per双酰亚胺染料的等温可逆荧光转换
    摘要:
    对于具有大而灵活的取代基的per双酰亚胺染料,已经实现了等温可重写的荧光机械致变色。机械刺激绘制的荧光图案可通过热刺激,溶剂蒸汽处理或从橙色荧光状态到绿色荧光状态的自发结构转变来消除。固体染料膜的等温荧光转换适用于显示器和感官材料。
    DOI:
    10.1002/adma.201201064
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文献信息

  • Isothermally Reversible Fluorescence Switching of a Mechanochromic Perylene Bisimide Dye
    作者:Norihiro Mizoshita、Takao Tani、Shinji Inagaki
    DOI:10.1002/adma.201201064
    日期:2012.7.3
    Isothermally rewritable fluorescence mechanochromism has been realized for a perylene bisimide dye with bulky and flexible substituents. Fluorescent patterns drawn by mechanical stimuli can be erased by thermal stimuli, treatment with solvent vapors, or spontaneous structural transition from orange‐fluorescent to green‐fluorescent states. The isothermal fluorescence switching of solid dye films is
    对于具有大而灵活的取代基的per双酰亚胺染料,已经实现了等温可重写的荧光机械致变色。机械刺激绘制的荧光图案可通过热刺激,溶剂蒸汽处理或从橙色荧光状态到绿色荧光状态的自发结构转变来消除。固体染料膜的等温荧光转换适用于显示器和感官材料。
  • Energy and Electron Transfer from Fluorescent Mesostructured Organosilica Framework to Guest Dyes
    作者:Norihiro Mizoshita、Ken-ichi Yamanaka、Satoru Hiroto、Hiroshi Shinokubo、Takao Tani、Shinji Inagaki
    DOI:10.1021/la204645k
    日期:2012.2.28
    Energy and electron transfer from frameworks of nanoporous or mesostructured materials to guest species in the nanochannels have been attracting much attention because of their increasing availability for the design and construction of solid photofunctional systems, such as luminescent materials, photovoltaic devices, and photocatalysts. In the present study, energy and electron-transfer behavior of dye-doped periodic mesostructured organosilica films with different host-guest arrangements were systematically examined. Fluorescent tetraphenylpyrene (TPPy)-silica mesostructured films were used as a host donor. The location of guest perylene bisimide (PBI) dye molecules, acting as an acceptor, could be controlled on the basis of the molecular design of the PBI substituent groups. PBI dyes with bulky substituents and polar anchoring groups were located at the pore surface with low self-aggregation, which induced efficient energy or electron transfer because of the close host-guest arrangement. However, PBI dye with bulky and hydrophobic substituents was located in the center of template surfactant micelles; the fluorescence emission from the host TPPy groups was hardly quenched when the host-guest distance was longer than the critical Forster radius (ca. 4.5 nm). The relationship between the energy or electron-transfer efficiency and the location of guest species in the channels of mesostructured organosilica was first revealed by molecular design of the PBI substituents.
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