[Ni(N'-(pyridine-4-carbonyl)-hydrazinecarbodithioic acid ethyl ester-H)(o-phenanthroline)2] | 1289595-94-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: [Ni(N'-(pyridine-4-carbonyl)-hydrazinecarbodithioic acid ethyl ester-H)(o-phenanthroline)2]
• 英文别名: [Ni(Hpchce)(o-phen)2]
• CAS: 1289595-94-3
• 化学式: CH₄O*C₃₃H₂₆N₇NiOS₂*Cl*H₂O
• 分子量: 744.948
• InChiKey: ICDXISDVJCLRPV-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 1,10-菲罗啉 、 nickel(II) chloride hexahydrate 、 N'-(pyridine-4-carbonyl)-hydrazinecarbodithioic acid ethyl ester 以 甲醇 为溶剂， 以55%的产率得到[Ni(N'-(pyridine-4-carbonyl)-hydrazinecarbodithioic acid ethyl ester-H)(o-phenanthroline)2]
  参考文献：
  名称：

  Synthesis, spectral and X-ray structural studies of Ni(II) complexes of N′-acylhydrazine carbodithioic acid esters containing ethylenediamine or o-phenanthroline as coligands

  摘要：

  The new complexes [Ni(Hbstbh)(2)(en)] (1) and [Ni(Hpchce)(o-phen)(2)]Cl center dot CH3OH center dot H2O (2) with N'-benzoyl hydrazine carbodithioic acid benzyl ester (H(2)bstbh) and [N'-(pyridine-4-carbonyl)-hydrazine]-carbodithioic acid ethyl ester (H(2)pchce) have been synthesized, containing ethylenediamine (en) or o-phenanthroline (o-phen) as coligands. The ligands and their complexes have been characterized by elemental analyses, IR, magnetic susceptibility and single crystal X-ray data. [Ni(Hbstbh)(2)(en)] (1) and [Ni(Hpchce)(o-phen)(2)]Cl center dot CH3OH center dot H2O (2) crystallized in the monoclinic and triclinic systems, space group C2/c and P - 1, respectively. The (N, O) donor sites of the bidentate ligands chelate the Ni(II) center and form a five-membered CN2ONi ring. The resulting complexes are paramagnetic and have a distorted octahedral geometry. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.12.043