bis(heptyloxymethyl)tellane | 1354835-62-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: bis(heptyloxymethyl)tellane
• 英文别名: Bis(heptyloxymethyl) tellane；1-(heptoxymethyltellanylmethoxy)heptane
• CAS: 1354835-62-3
• 化学式: C₁₆H₃₄O₂Te
• 分子量: 386.045
• InChiKey: KZGXHILWBMLWJK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.58
• 重原子数：
  19
• 可旋转键数：
  16
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  bis(heptyloxymethyl)tellane 以 二氯甲烷 为溶剂， 生成 bis(heptyloxymethyl)ditellane
  参考文献：
  名称：

  Reactions of chloromethyl heptyl ether with selenium and tellurium in the system hydrazine hydrate-potassium hydroxide

  摘要：

  Chloromethyl heptyl ether reacts with selenium in the system hydrazine hydrate-potassium hydroxide with formation of a mixture of bis(heptyloxymethyl)selane (32%) and bis(heptyloxymethyl)diselane (64%). Reductive cleavage of the latter with hydrazine hydrate-KOH and subsequent alkylation with methyl iodide gave methyl(heptyloxymethyl) selane in 94% yield. Analogous reaction of tellurium with hydrazine hydrate-KOH leads to the formation of extremely unstable bis(heptyloxymethyl) ditellane and bis(heptyloxymethyl) tellane at a ratio of 1 : 4.

  DOI：

  10.1134/s1070428011120049
• 作为产物：
  描述：

  1-chloromethoxy-heptane 在 碲化氢 、 一水合肼 、 potassium hydroxide 作用下， 反应 2.0h， 以36%的产率得到正庚醇
  参考文献：
  名称：

  Reactions of chloromethyl heptyl ether with selenium and tellurium in the system hydrazine hydrate-potassium hydroxide

  摘要：

  Chloromethyl heptyl ether reacts with selenium in the system hydrazine hydrate-potassium hydroxide with formation of a mixture of bis(heptyloxymethyl)selane (32%) and bis(heptyloxymethyl)diselane (64%). Reductive cleavage of the latter with hydrazine hydrate-KOH and subsequent alkylation with methyl iodide gave methyl(heptyloxymethyl) selane in 94% yield. Analogous reaction of tellurium with hydrazine hydrate-KOH leads to the formation of extremely unstable bis(heptyloxymethyl) ditellane and bis(heptyloxymethyl) tellane at a ratio of 1 : 4.

  DOI：

  10.1134/s1070428011120049