[Zn(imidazole)2(pyridine 2,6-dicarboxylate)]*H2O | 1224507-69-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [Zn(imidazole)2(pyridine 2,6-dicarboxylate)]*H2O
• 英文别名: [Zn(imH)2(pdc)]*H2O
• CAS: 1224507-69-0
• 化学式: C₁₃H₁₁N₅O₄Zn*H₂O
• 分子量: 384.667
• InChiKey: OOLVBFPIHPXRPS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  咪唑 、 吡啶-2,6-二甲酸 、 zinc(II) perchlorate 、 水 以 水 为溶剂， 以38%的产率得到[Zn(imidazole)2(pyridine 2,6-dicarboxylate)]*H2O
  参考文献：
  名称：

  Metal–organic open frameworks with one-dimension channels assembled with pyridine 2,6-dicarboxylic acid and N-containing auxiliary ligands: Syntheses, crystal structures, and physical characterization

  摘要：

  Four new complexes, {[Mn(imH)(2)(pdc)]center dot H2O}(n) (1), [Zn-2(pdc)(2)(H2O)(5)]center dot 2H(2)O (2), [Zn(imH)(2)(pdc)]center dot H2O (3), {[Zn-2(pdc)(2)(bpy)(H2O)(2)]center dot 5H(2)O}(n) (4) [imH = imidazole pdc = pyridine 2,6-dicarboxylate, bpy = 4,4'-bipyridine] have been synthesized under hydrothermal conditions and structurally characterized by elemental analysis, IR, PXRD, single-crystal X-ray diffraction and thermogravimetric analyses. All the four complexes display a three-dimensional (3D) open framework with one-dimensional (1D) channels that are filled with lattice water molecules. Particularly, in 4, the lattice water molecules form an infinite water chain. Both 1 and 4 consist of 1D polymeric chains. While 2 contains a dinuclear Zn(II) unit, and 3 is a mononuclear complex. Further, the result of thermal analysis of 1 and 2 shows the robustness of the overall supramolecular three-dimensional architecture. Complexes 1, 3, and 4 exhibit strong fluorescent emissions in the solid state at room temperature and could be significant in the field of photoactive materials. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.12.044