hydroxylamine*CO | 651004-21-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: hydroxylamine*CO
• 英文别名: Carbon monoxide;hydroxylamine；carbon monoxide;hydroxylamine
• CAS: 651004-21-6
• 化学式: CO*H₃NO
• 分子量: 61.0403
• InChiKey: GXMCSZMEIFHLIY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.7
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  47.2
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  氨基甲酸 以 gaseous matrix 为溶剂， 生成 、 Carbon Monoxide Hydrate 、 hydroxylamine*CO 、 一氧化碳 、 二氮烯
  参考文献：
  名称：

  VUV irradiation of carbon dioxide (CO2) and ammonia (NH3) complexes in argon matrix

  摘要：

  In this study, we characterized by FTIR spectroscopy the 1:1 and 2:1 molecular complexes between NH3 and CO2 in argon matrix at low temperature. In addition we tentatively identified the 1:2 molecular complex. The structures of the complexes were established from B3LYP calculations. Moreover, we showed that the VUV irradiation of the 1:1 complex forms the NH2OH:CO complex. (c) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.chemphys.2008.10.026

文献信息

• VUV irradiation of carbon dioxide (CO2) and ammonia (NH3) complexes in argon matrix
  作者：J.B. Bossa、F. Duvernay、P. Theulé、F. Borget、T. Chiavassa

  DOI：10.1016/j.chemphys.2008.10.026

  日期：2008.12

  In this study, we characterized by FTIR spectroscopy the 1:1 and 2:1 molecular complexes between NH3 and CO2 in argon matrix at low temperature. In addition we tentatively identified the 1:2 molecular complex. The structures of the complexes were established from B3LYP calculations. Moreover, we showed that the VUV irradiation of the 1:1 complex forms the NH2OH:CO complex. (c) 2008 Elsevier B.V. All rights reserved.