| 227099-86-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• CAS: 227099-86-7
• 化学式: C₁₅H₁₅CuN₇*ClO₄
• 分子量: 456.328
• InChiKey: FXNXXDVVMSYAGT-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  吡啶 、 tetrakis(acetonitrile)copper(I) perchlorate 、 三(吡唑)甲烷 以 吡啶 、 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Copper(I)-induced activation of dioxygen for the oxidation of organic substrates under mild conditions. An evaluation of ligand effects

  摘要：

  Under the appropriate reaction conditions and stoichiometries the combination of a Cu(I) complex, t-BuOOH and molecular oxygen generates a catalyst that is capable of oxidizing alkanes, alkenes, alcohols and triphenyl phosphine under one atmosphere oxygen pressure and at room temperature. Particularly impressive is the performance of those catalysts over substrates containing allylic methylenes in terms of both reaction efficiencies and selectivities. For instance, for ethylbenzene the system 3 5 mM/t-BuOOH 10 mM; O-2 1 atm/PhCH2Me 1 M in ac:py (1:2) as the solvent forms 57.7 mM acetophenone. Cyclohexene under similar reaction conditions yields 85.4 mM 2-cyclohexene-1-one and 3.5 mM 2-cyclohexene-1-ol. (C) 1999 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1381-1169(98)00278-7