Zn(H2O)2(4-(4-acetophenylaminoisonitrosoacetyl)biphenyl(-1H))2 | 947254-04-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Zn(H2O)2(4-(4-acetophenylaminoisonitrosoacetyl)biphenyl(-1H))2
• CAS: 947254-04-8
• 化学式: C₄₄H₃₈N₄O₈Zn
• 分子量: 816.198
• InChiKey: MPGFMFUYFSYDPW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4-(4-acetophenylaminoisonitrosoacetyl)biphenyl 、 zinc(II) acetate dihydrate 在 KOH 作用下， 以 乙醇 为溶剂， 以74%的产率得到Zn(H2O)2(4-(4-acetophenylaminoisonitrosoacetyl)biphenyl(-1H))2
  参考文献：
  名称：

  Synthesis and characterization of new ketooximes and their complexes

  摘要：

  The starting point of the research was the reaction of chloroacetyl chloride with biphenyl in the presence of aluminum chloride. 4-Biphenylhydroximoyl chloride (HL) was obtained by reacting synthesized 4-(chloroacetyl)biphenyl with alkyl nitride. Four new substituted 4-(alkylaminoisonitrosoacetyl)biphenyles (ketooximes) were prepared by reacting 4-biphenylhydroximoyl chloride with corresponding amines in EtOH. The following amines were used for ligands: p-toluidine, p-chloroaniline, pyrrolidine, and 4-aminoacetophenone. Mononuclear complexes with a metal-ligand ratio of 1: 2 were prepared using cadmium(II), cobalt(II), copper(II), nickel(II), lead(II), and zinc(II) salts. These compounds have been characterized by elemental analyses, AAS, infrared spectra and magnetic susceptibility measurements. The ligands have been further characterized by H-1 NMR. The results suggest that the ketooximes act as bidentate ligands which bond metal ions through the oxime and carbonyl oxygen.

  DOI：

  10.1134/s0036023606090105