(1,10-phenanthroline)[(2-pyridyl)thiophene-3-ido]palladium(II) nitrate | 943984-83-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: (1,10-phenanthroline)[(2-pyridyl)thiophene-3-ido]palladium(II) nitrate
• 英文别名: [Pd(tpy)(phen)]NO3
• CAS: 943984-83-6
• 化学式: C₂₁H₁₄N₃PdS*NO₃
• 分子量: 508.853
• InChiKey: KGBAWXHJIFPNDN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 [Pd(μ-Cl)(2-(2'-thienyl)pyridine)]2 、 silver nitrate 以 乙腈 为溶剂， 以58%的产率得到(1,10-phenanthroline)[(2-pyridyl)thiophene-3-ido]palladium(II) nitrate
  参考文献：
  名称：

  Spectroscopic and electrochemical properties of mixed-ligand cyclopalladinized complexes of deprotonated forms of 2-(2-thienyl)pyridine and 2-phenylpyridine with 1,10-phenantroline and its 1,4-diazine derivatives

  摘要：

  A comparative study of [Pd((NC)-C-boolean AND)((NN)-N-boolean AND)](+) complexes {((NC)-C-boolean AND)(-) are deprotonated forms of 2-phenylpyridine and 2-(2-thienyl)pyridine and ((NN)-N-boolean AND) is 1,10-phenantroline, dipyrido[f,h]quinoxaline, dipyrido[a,c]phenazine or 6,7-dicyanodibenzo[f,h]quinoxaline} was carried out by the methods of H-1 NMR, electronic absorption and emission spectroscopy, and cyclic voltammetry. Optical and electrochemical properties of dipyrido-substituted 1,4-diazines are conditioned by the electron transfer involving pi* orbitals localized on weakly interacting phenantroline (pi(*)(phen)) and diazne (pi(*)(diaz)) components.

  DOI：

  10.1134/s1070363206070267